4.7 Article

Effect of preparation methods on the performance of CeO2/Al2O3 catalysts for selective catalytic reduction of NO with NH3

Journal

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 19, Issue 6, Pages 2022-2025

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2013.03.010

Keywords

SCR; CeO2/Al2O3 Preparation; Characterization

Funding

  1. Scientific Problem Tackling Program of Science and Technology Commission of Shanghai Municipality [11dz2281700, 10dz120140, 10dz1 201402]
  2. Innovation Program of Shanghai Municipal Education Commission [10YZ155]
  3. Choose and Cultivation of Excellent Young Teachers Program of Shanghai Municipal Education Commission [sd109008]
  4. Talent Induction Program of Shanghai University of Electric Power [K-2009-03]

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CeO2/Al2O3 catalysts prepared by three methods were investigated for selective reduction of NO with NH3. It was found that the catalyst prepared by the single step sol-gel method had the best SCR activity and SO2 resistance performance. From the results of BET, XRD, TPD and TPR, it can be concluded that large surface area, strong interaction, highly dispersed nano-crystalline ceria, high NH3 adsorption capacity and good redox ability might be the main reasons for the excellent performance of CeO2/Al2O3 catalyst prepared by the single step sol-gel method. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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