Journal
ORGANIC LETTERS
Volume 17, Issue 17, Pages 4244-4247Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02037
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Funding
- NSF of China [21172023]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
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A challenging selective intermolecular cross-coupling and homocoupling of aryl-aryl or aryl-alkyl diazo compounds has been accomplished via a copper system, which afforded tetrasubstituted olefins in moderate to high yields with good to excellent Z-selectivity. This novel methodology enables rapid synthesis of tetrasubstituted olefins, which would find broad application in accessing maleimide libraries of nature products and bioactiye small molecules.
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