Journal
ORGANIC LETTERS
Volume 17, Issue 14, Pages 3596-3599Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01693
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Funding
- European Research Council under the European Union's Seventh Framework Programme (FP7)/ERC [277588]
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The first total synthesis of pandamarine, an alkaloid isolated from Pandanus amaryllifolius is reported. The key step of this extremely short (six steps in total) and protecting group-free synthesis is a highly efficient cascade reaction sequence initiated by the photooxidation of an easily accessible, and symmetric difuran precursor.
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