Journal
ORGANIC LETTERS
Volume 17, Issue 18, Pages 4424-4427Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02026
Keywords
-
Categories
Funding
- SERB, New Delhi [SB/S1/OC-63/2013]
- CSIR, New Delhi
Ask authors/readers for more resources
The first catalytic enantioselective 1,4-iodofunctionalizations of conjugated dienes have been developed. Starting from beta,gamma,delta,epsilon-unsaturated oximes and 4-Ns hydrazones, these N-iodosuccinimide-mediated reactions are catalyzed by newly modified tertiary aminothiourea derivatives and furnish Delta(2)-isoxazoline and Delta(2)-pyrazoline derivatives, respectively, containing an (E)-allyl iodide group at the quaternary stereogenic center generally in high yield and with excellent enantioselectivity (up to 98.5:1.5 er).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available