Journal
ORGANIC LETTERS
Volume 17, Issue 15, Pages 3822-3825Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01797
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Funding
- MEXT
- AMED
- Grants-in-Aid for Scientific Research [26105726] Funding Source: KAKEN
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A novel catalytic system using I-2 and PhSiH3 for the intramolecular hydroalkoxylation of unactivated alkenes is described. NMR study indicated that in situ generated PhSiH2I is a possible active catalytic species. This catalytic system allows an efficient intramolecular hydroalkoxylation of phenyl-, trialkyl-, and 1,1-dialkyl-substituted alkenes as well as a variety of unactivated monoalkyl- and 1,2-dialkyl-substituted alkenes at room temperature. Mechanistic consideration based on significant experimental observations is also discussed.
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