Journal
ORGANIC LETTERS
Volume 17, Issue 17, Pages 4288-4291Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02097
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Funding
- Natural Science and Engineering Research Council of Canada (NSERC)
- Canada Research Chair Program
- Canada Foundation for Innovation
- FRQNT Centre in Green Chemistry and Catalysis
- Universite de Montreal
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Chiral fluorocyclopropyl carbinols were synthesized in high diastereoselectivities via a zinc mediated cyclopropanation reaction, using sec-allylic alcohols as simple building blocks. An enantioselective version of this transformation was achieved through in situ formation of chiral allylic zinc sec-alkoxides from the requisite aldehydes using Walsh's protocol.
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