Journal
ORGANIC LETTERS
Volume 18, Issue 2, Pages 240-243Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03380
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- University of Geneva
- Swiss National Science Foundation
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Reactions of alpha-diazo-beta-ketoesters with cyclic ketones, lactones, and carbonates are reported. Thanks to the combined use of salt [CpRu(CH3CN)(3)][BArF] and 1,10-phenanthroline as catalyst for the diazo decomposition, effective and practical syntheses of spiro bicyclic ketals, orthoesters, and orthocarbonates are afforded.
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