Journal
ORGANIC LETTERS
Volume 17, Issue 24, Pages 6018-6021Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02983
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Funding
- MEXT [21245028, 25708018, 15H05803]
- JST, Advanced Catalytic Transformation Program for Carbon Utilization (ACT-C), Japan
- Grants-in-Aid for Scientific Research [25708018, 15H01087, 15K13642, 15H03779, 15H05803] Funding Source: KAKEN
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A nickel(0)/chiral N-heterocyclic carbene (NHC)-catalyzed fully intermolecular, enantioselective [2 + 2 + 2] cycloaddition of two enones and an alkyne has been developed to access enantioenriched cyclohexenes. A single diastereomer was obtained with a successive generation of four contiguous stereogenic centers. The absolute configuration of cyclohexene derivative 3aa was determined by X-ray diffraction and circular dichroism (CD) spectral studies.
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