Journal
ORGANIC LETTERS
Volume 17, Issue 16, Pages 3956-3959Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01779
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Funding
- National Basic Research Program of China (973 program) [2011CB808600]
- National Natural Science Foundation of China [21172221]
- Chinese Academy of Sciences
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A highly enantioselective 6-exo-bromoamino-cyclization of (E)-homoallylic N-tosylcarbamates catalyzed by a novel monophosphine-Sc(OTf)(3) complex is described, giving A wide variety Of optically active oxazinanones with high enantioselectivities.
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