Journal
ORGANIC LETTERS
Volume 17, Issue 4, Pages 1006-1009Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00115
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Funding
- Italian MIUR [PRIN 20109Z2XRJ_006]
- Centro di Tecnologie Integrate per la Salute, Universita di Salerno [PONa3_00138]
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The TFPB superweak anion effectively induces the threading of a scarcely preorganized calix[6]arene (1) with weakly interacting tertiary ammonium axles (2(+)3(+)). The pseudorotaxanes (4(+)5(+)) thus formed show an unexpected chirality due to an unprecedented formation of a threading-induced stereogenic ammonium center.
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