Journal
ORGANIC LETTERS
Volume 17, Issue 5, Pages 1208-1211Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00156
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Funding
- NSF [CHE-1362057, CHE-1228336]
- Direct For Mathematical & Physical Scien [1228336, 1362057] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1336071, 1619590] Funding Source: National Science Foundation
- Division Of Chemistry [1362057, 1228336] Funding Source: National Science Foundation
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Radical addition to vinyltriazole was developed as a new approach to achieve 1,2,3-triazole ring opening under mild conditions. Through reagent control, excellent chemoselectivity was achieved, giving either nitrile under basic conditions or quinoxaline under neutral conditions. Reactivities made this method an attractive new reaction mode.
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