Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 4, Pages 1013-1016Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02419b
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Funding
- National Science Foundation of China [20802079, 21222207]
- National Basic Research Program of China [2011CB808600]
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An enantioselective hydrosilylation of imines was successfully achieved using a chiral borane catalyst generated by the in situ hydroboration of a binaphthyl-based chiral diene with Piers' borane HB(C6F5)(2) to furnish a variety of optically active amines in 70% to >99% yields and 44-82% ees.
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