Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 42, Pages 10505-10510Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01630d
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Funding
- Australian Renewable Energy Agency within the Australian Centre for Advanced Photovoltaics
- Australian Research Council Future Fellowship [FT130100500]
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The regioselective synthesis of fullerene multiadducts was achieved from commercially available reagents in one pot over two steps. The configuration of the isolated regioisomers was determined using various NMR methods, UV-vis spectroscopy and electrochemical analysis with the structure of one isomer confirmed by single crystal X-ray analysis. Interesting variation in regioselectivity was observed when different amino acid reagents were used in the reactions. Theoretical calculations and additional experiments, such as deuterium exchange, led to a proposed mechanism for the regioselective product formation.
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