4.6 Article

A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 9, Pages 2555-2560

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02543a

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Funding

  1. Engineering and Physical Sciences Research Council [EP/J003921/1] Funding Source: researchfish
  2. EPSRC [EP/J003921/1] Funding Source: UKRI

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A combined experimental and computational study suggests that a reduction in the entropy of activation in the solid state can lead to the protodeboronation of boronic acids.

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