4.4 Article

Synthesis and Molecular Recognition of Novel Multiimidazole Cyclophanes

Journal

JOURNAL OF HETEROCYCLIC CHEMISTRY
Volume 46, Issue 6, Pages 1137-1141

Publisher

WILEY
DOI: 10.1002/jhet.188

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Cyclophanes based on 2,2'-biimidazole and 2,2'-bibenzimidazole were synthesized as receptors. UV spectroscopic titration in chloroform at 25 degrees C showed 1:1 complexes between the cyclophanes and the guests, and the binding constants (K) and Gibbs free energy changes (-Delta G(0)) were calculated according to the modified Benesi-Hildebrand equation.

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