4.7 Article

Promoting effect of alkaline earth metal doping on catalytic activity of HC and NOx conversion over Pd-only three-way catalyst

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 279, Issue -, Pages 226-235

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2014.06.076

Keywords

Alkaline earth; Ce0.67Zr0.33O2; Structural promotion; Pd-only three-way catalyst

Funding

  1. Ministry of Science and Technology of the People's Republic of China [2011AA03A406]
  2. Zhejiang Leading Team of Science and Technology Innovation [2009R50020]

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The influence of alkaline earth metal (M = Mg, Ca, Sr and Ba) promoter on the structural/textural properties of Ce0.67Zr0.33O2 (designated as CZ) and the catalytic behavior of its supported Pd-only three-way catalyst (Pd/CZM) have been investigated. The results show that the modification with alkaline earth metal obviously improves the catalytic activity for hydrocarbon (HC) and nitrogen oxides (NOx) conversion, especially the introduction of Ba. Furthermore, the operation window of the promoted catalysts has also been widened. The doping of alkaline earth metal leads to the formation of more homogeneous Ce-Zr-M ternary solid solution with higher surface area and smaller crystallite size, and the corresponding Pd/CZM catalysts present improved reducibility of PdO species. The modification with Ca, Sr and Ba improves the thermal aging resistance, especially Ba. DRIFTS results reveal that the doping of alkaline earth metal enhances the oxygen and electron transfer ability and favors the dissociation of NO, which promotes the activation and storage capacity of the acidic atoms like NOx, and leads to enhanced catalytic activity performance. (C) 2014 Elsevier B.V. All rights reserved.

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