4.7 Article

Novel phenol capturer derived from the as-synthesized MCM-41

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 190, Issue 1-3, Pages 87-93

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2011.02.089

Keywords

Instantaneous adsorption of phenol; Zeolite; Amine coated as-synthesized MCM-41; Tobacco smoke; Environment protection

Funding

  1. National Basic Research Program of China [2007CB613301]
  2. Ministry of Science and Technology of China [2008AA06Z327]
  3. NSF of China [20773601, 20873059, 20871067]
  4. Scientific Research Foundation of Graduate School
  5. Analysis Centre of Nanjing University

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Novel phenol-capturer was prepared by modifying the as-synthesized mesoporous silica MCM-41 with tetraethylenepentamine (TEPA), not only saving the energy and time for removal of template, but also opening the way to utilize the micelles for adsorption. Once the organic modifier was distributed in the template micelle of MCM-41 to form a web within the mesoporous channel, the composite could adsorb more phenols in gas stream than activated carbon for the first time. With an unwonted high adsorption capacity, this mesoporous silica-amine composite represented potential application for trapping phenols, especially in tobacco smoke to protect environment. (C) 2011 Elsevier B.V. All rights reserved.

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