Article
Electrochemistry
Manjunatha Palanna, Shambhulinga Aralekallu, C. P. Keshavananda Prabhu, Veeresh A. Sajjan, Mounesh, Lokesh Koodlur Sannegowda
Summary: A novel CoTABImPc was synthesized and characterized for the first time, showing high electrocatalytic activity for the detection of Hg(II) ions. The polymeric film electrode exhibited good sensitivity and low detection limits for Hg(II) detection at nanomolar concentrations, demonstrating its potential application in environmental pollution analysis.
ELECTROCHIMICA ACTA
(2021)
Article
Environmental Sciences
Ruslan Heriberto de Diego Almeida, Fabiola Monroy-Guzman, Carlos Rosendo Arganis Juarez, Juan Manriquez Rocha, Erika Bustos Bustos
Summary: This study demonstrates the successful detection and quantification of actinides including Th, U, Pu, Am, and Cm in aqueous media at ppt level using modified graphite electrodes with phthalocyanine. By modeling the cyclic voltammetry data with Aoki's model, the electrochemical methods show great potential for identifying and quantifying actinides.
Article
Chemistry, Physical
Shuting Wei, Haiyuan Zou, Weifeng Rong, Fuxiang Zhang, Yongfei Ji, LeLe Duan
Summary: The utilization of intermittent renewable electricity for CO2 reduction requires high-performance catalysts with large current density and high selectivity for the target products. Ni phthalocyanine polymer demonstrates superior catalytic activity and high selectivity for CO2-to-CO conversion in a wide operating potential window, emphasizing the importance of modulating the structure and hydrophobicity of nanostructured catalysts for enhancing CO2RR performance.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Analytical
Yen-Jou Chen, Yu-Ren Peng, Hung-Yu Lin, Tsung-Yu Hsueh, Chao-Sung Lai, Mu-Yi Hua
Summary: The tumor suppressor protein p53 plays a crucial role in regulating cell cycle and apoptosis, with potential implications for cancer prevention. This study demonstrates the use of a modified electrode for detecting p53 antigen, offering promising clinical applications.
Article
Chemistry, Analytical
Yu Chen, Wei Li, Jianlin Li, Siqi Zhuo, Saisai Jiao, Siwei Wang, Jialong Sun, Qianjin Li, Tiesong Zheng
Summary: An electrochemical sensor for bisphenol A (BPA) based on a stable three-dimensional porous silicon-carbon-gold (3D PS-C-Au) electrode was developed, showing good stability and detection performance. The sensor has great potential application in food and environmental safety fields.
MICROCHEMICAL JOURNAL
(2021)
Article
Energy & Fuels
Giddaerappa, Nemakal Manjunatha, Shantharaja, Mirabbos Hojamberdiev, Lokesh Koodlur Sannegowda
Summary: In this study, a novel nitrogen-rich palladium amide bridge hippuric acid phthalocyanine complex (PdTAHAPc) is synthesized and combined with multi-walled carbon nanotubes to prepare a hybrid composite electrode. The hybrid composite electrode exhibits superior specific capacitance and stability in sulfuric acid electrolyte.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Materials Science, Multidisciplinary
Lekhetho S. Mpeta, Pinar Sen, Refilwe Matshitse, Tebello Nyokong
Summary: This study reports the potential application of nickel phthalocyanines nanoparticles (NPs)-detonation nanodiamonds (DNDs) as platforms for the electrocatalytic detection of nitrite. The modified electrode surfaces showed enhanced electron transfer ability, with (1)-NPs-DNDs exhibiting better electron tranter ability. The electrocatalytic performance of the modified surfaces towards nitrite oxidation was investigated, and (1)-NPs-DNDs demonstrated superior performance in terms of oxidation potential, current, and limit of detection, making it a promising sensor for nitrite.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Chemistry, Applied
Joanna Szymczak, Tomasz Rebis, Michal Kotkowiak, Barbara Wicher, Lukasz Sobotta, Ewa Tykarska, Jadwiga Mielcarek, Michal Kryjewski
Summary: Three regioisomers of L-menthol-substituted magnesium(II) phthalocyanine were obtained and characterized, with one of them having its crystal structure determined. The compounds exhibited maxima in the Q-band, varying quantum yields for fluorescence and singlet oxygen generation, as well as specific oxidation and reduction behaviors in voltammetric studies. DFT methods were used to calculate IR and UV-Vis spectra and optical band gap.
Article
Chemistry, Physical
Alicja Stachowiak, Kamil Kedzierski, Boleslaw Barszcz, Kamil Kotwica, Danuta Wrobel
Summary: Spectroscopic and electrochemical studies were conducted to determine the energy gaps of four commercially available phthalocyanines, revealing the influence of molecular structure on the energy gaps. Experimental results were highly compatible with DFT calculations, but MP2 method results showed significant discrepancies with both.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Amanda Leda, Mina Hassani, Tomasz Rebis, Michal Falkowski, Jaroslaw Piskorz, Dariusz T. Mlynarczyk, Peter McNeice, Grzegorz Milczarek
Summary: A new metal complex was synthesized by metallating a metal-free porphyrazine derivative with nickel(II) ions. The purity of the complex was confirmed using various analytical techniques. The complex was combined with different carbon nanomaterials to create hybrid electroactive electrode materials. The electrocatalytic properties of the complex on various carbon nanostructures were extensively studied, and a modified electrode using MWCNTs showed the best electrocatalytic properties for hydrogen peroxide oxidation/reduction. The prepared sensor showed a linear response to H2O2 and could be potentially used in biomedical and environmental applications.
Article
Electrochemistry
Sara Grecchi, Serena Arnaboldi, Abdirisak Ahmed Isse, Chiara D'Aloi, Armando Gennaro, Patrizia R. Mussini
Summary: A comparative investigation on the electrochemical activity of substituted bromothiophenes vs bromobenzenes highlights the combined effects of the aromatic or heteroaromatic ring substituents and the sulphur atom on both the intrinsic reactivity and the reactivity in the presence of electro-catalytic effects. The presence of sulphur atom significantly promotes the process in both non-catalytic conditions and on catalytic electrodes, acting as an adsorption auxiliary. The nitrile group may also act as an additional adsorption auxiliary.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Bhanupriya Brahma, Sarani Sen, Priyabrata Sarkar, Ujjaini Sarkar
Summary: A rapid sensing system was developed for quantifying p-Chloro-meta-Xylenol (PCMX) in wastewater samples, utilizing a unique polymeric nanocomposite modified electrode with excellent sensitivity and stability. The optimized combination of constituents and electrochemical techniques yielded a interference-free response with good selectivity, reproducibility, and repeatability. The sensing platform demonstrated applicability for real samples and showed good correlation with standard methods.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Analytical
Marta Domzalska, Aleksandra M. Dabrowska, Dawid Chojnowski, Mariusz Makowski, Agnieszka Chylewska
Summary: Researchers are developing a universal method to detect pyrazine derivatives in body fluids in order to prevent side effects. By electropolymerizing GCE surfaces, three types of modified electrodes were prepared and used as chemosensors for four pyrazine drugs in stoichiometric tests, providing detailed analysis and comparison.
Article
Chemistry, Physical
David Possetto, Ilir Pecnikaj, Gabriela Marzari, Simonetta Orlandi, Silvia Sereno, Marco Cavazzini, Gianluca Pozzi, Fernando Fungo
Summary: This study demonstrates the relationship between the monomer molecular structure and the capability of tuning the morphology of electrodeposited gas bubbles template polymer thin films. By adjusting electrochemical parameters, the nanostructural properties of the soft-templated films can be fine-tuned, resulting in superhydrophobic surfaces.
Article
Electrochemistry
Marco Bonechi, Walter Giurlani, Andrea Stefani, Andrea Marchetti, Massimo Innocenti, Claudio Fontanesi
Summary: The electrochemical oxidation of resorcinol was experimentally investigated on platinum, palladium, and glassy carbon electrodes. Extensive electrochemical characterization was conducted, and the results were integrated with complementary chromatographic analytical techniques: LC-DAD and LC-MS. It was demonstrated that resorcinol can efficiently and easily polymerize during electrochemical oxidation, forming a polymer film with good adhesion on the electrode surface.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Mbulelo Jokazi, Lekhetho S. Mpeta, Tebello Nyokong
Summary: Manganese and cobalt metalated porphyrins attached to graphene quantum dots showed improved electrocatalytic activity for the oxidation of hydrazine, with CoTA(3)CPP-GQDs exhibiting the best catalytic rate constants and lowest limits of detection.
Article
Biochemistry & Molecular Biology
Pinar Sen, Azole Sindelo, Nnaemeka Nnaji, John Mack, Tebello Nyokong
Summary: Novel mono- and dipyridylvinyl boron dipyrromethene dyes were prepared and compared to the corresponding core dyes for their photodynamic antimicrobial chemotherapy (PACT) activities. Results showed that the spectral properties of the dyes and the generation of singlet oxygen could be controlled through pyridylvinyl substitution and iodine atom incorporation, but the pi-extended dyes had lower activities compared to the core dye.
PHOTOCHEMISTRY AND PHOTOBIOLOGY
(2023)
Article
Oncology
Yolande Ikala Openda, Tebello Nyokong
Summary: Photodynamic antimicrobial chemotherapy (PACT) combined with ciprofloxacin (CIP) effectively reduces the biofilm cell survival of antibiotic-resistant S. aureus and E. coli strains. PACT alone shows no significant activity, while CIP alone exhibits some inhibitory activity. The combination treatment completely eradicates mature biofilms.
PHOTODIAGNOSIS AND PHOTODYNAMIC THERAPY
(2023)
Article
Materials Science, Multidisciplinary
Lindokuhle Cindy Nene, Tebello Nyokong
Summary: This study presents the preparation of cationic thiazole phthalocyanines (Pcs) conjugates with nitrogen doped (NGQDs) and nitrogen/sulfur co-doped (NSGQDs) graphene quantum dots (GQDs). The photo-sonodynamic combinatorial therapy (PSDT) activities of the conjugates were tested in vitro with cancer cell lines. The conjugates exhibited the production of reactive oxygen species (ROS) through the treatment technique. The Pc-GQDs generated singlet oxygen and hydroxyl radicals when exposed to light and low frequency ultrasound in PSDT. Cancer eradication was observed in vitro for the PSDT treatment using the Pc-GQDs conjugates. The NGQDs conjugates performed better in terms of ROS generation and cell eradication compared to the NSGQDs conjugates. The PSDT treatments showed increased ROS generation and cancer eradication efficiencies compared to PDT and SDT monotreatments.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Nobuhle Ndebele, Tebello Nyokong
Summary: This study presents the non-covalent conjugation of carbon-based nanomaterial with tris(4-tert-butylphenoxy)-(5-phenoxylpicolinic acid) phthalocyanato cobalt (II) (CoPc). The hybrids of CoPc with graphene quantum dots (GQDs), nitrogen-doped quantum dots (NGQDs), and single-walled carbon nanotubes (SWCNTs) were successfully synthesized and characterized. The electrochemical analysis showed that the CoPc and its conjugates exhibited good nitrite detection capabilities, with sensitivities (3-28 mu A mu M-1), catalytic rate constants (1.8 x 102-5.42 x 104 M-1 s-1), and limits of detection (0.17-1.70 mu M) comparable to those in literature.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Lindokuhle Cindy Nene, Tebello Nyokong
Summary: This study investigates the effects of ultrasonic frequency and power on the stability, reactive oxygen species yields, and cytotoxicity activities of different substituted ionic phthalocyanines (Pcs) in sonodynamic therapy (SDT). The degradation of Pcs increases with increasing power at Par II. Two reactive oxygen species, singlet oxygen and hydroxyl radicals, were detected in ultrasound treated Pcs. Par I was chosen for SDT, photodynamic therapy (PDT), and photo-sonodynamic therapy (PSDT) due to minimal degradation of most Pcs. PSDT generally shows improved therapeutic efficacies compared to SDT and PDT mono treatments.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Nnamdi Nwahara, Garth Abrahams, John Mack, Earl Prinsloo, Tebello Nyokong
Summary: This study presents a liposome loaded-silicon (IV) phthalocyanine (SiPc) with naphthoquinone axial ligands as hypoxia-responsive prodrug-like moieties (Prodrug-SiPc). Computational methods were used to assess the photophysical, photochemical and electrochemical redox properties of Prodrug-SiPc, revealing the relationship between material structure and properties. The liposomal encapsulation of Prodrug-SiPc resulted in potential photodynamic therapy (PDT) drug candidates, which took advantage of the hypoxic microenvironment of tumors to enhance therapeutic efficacy compared to typical PDT.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2023)
Article
Chemistry, Physical
Lindokuhle Cindy Nene, Tebello Nyokong
Summary: This study explores the effects of gold and silver nanoparticles on the in vitro anticancer photo and sono-dynamic therapy and their combination therapy using cationic thiazole-phthalocyanines. The results show that conjugation to nanoparticles increases the generation of oxygen species and the combination therapy exhibits higher anticancer activity compared to monotherapies.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Gugu Kubheka, Nthabeleng Molupe, John Mack, Tebello Nyokong
Summary: The ease of functionalization of BODIPY dyes allows for the preparation of pH indicators by introducing suitable functional groups. In this study, two dimethylamino substituted BODIPY dyes were synthesized and characterized, and their photophysical properties and pH response were investigated.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2023)
Article
Chemistry, Applied
Chenming Chan, Jia Li, Jianwei Wu, Youchun Zi, Zhaoli Xue, Mahlatse Ledwaba, John Mack, Tebello Nyokong
Summary: Due to the significant hazardous impact of Hg2+ on the environment and ecosystem, there is a need for highly sensitive and selective Hg2+ probes. A new imidazole-based Hg2+ probe has been synthesized and characterized, which can detect Hg2+ through an ion-specific co-ordination mechanism. The probe exhibits significant fluorescence enhancement in acetonitrile solutions containing Hg2+, with a limit of detection of 0.30 mu M. Additionally, it shows utility in detecting Hg2+ in biochemical systems and the environment based on paper test strip and HeLa cell experiments.
Article
Chemistry, Analytical
Lunathi Ncwane, Lekhetho S. Mpeta, Tebello Nyokong
Summary: This study investigates the effect of detonation nanodiamonds (DNDs) on the electrocatalytic properties of an asymmetrically substituted cobalt phthalocyanine (CoPc). The addition of DNDs enhances the electrochemical behavior of CoPc. Various modifications of glassy carbon electrode (GCE) were made using CoPc alone, CoPc-DNDs(pi pi) or CoPc@DNDs, and the sequential addition of CoPc and DNDs. Among these modifications, GCE/CoPc@DNDs showed the best electrocatalytic activity for the detection of hydrazine, with a catalytic rate of 9.3x10(4) M-1.s(-1) and a detection limit of 0.33 mu M.
Article
Oncology
Aviwe Magadla, Yolande Ikala Openda, Lekhetho S. Mpeta, Tebello Nyokong
Summary: In this study, we synthesized three phthalocyanine complexes and investigated their effects on photodynamic antimicrobial chemotherapy (PACT) against E.coli and S.aureus in both planktonic and biofilm forms. Complex 4, with 8 cationic charges, showed the highest activity against the biofilms. Surface stability of E.coli and S.aureus biofilms in the presence of complex 4 was analyzed using cyclic voltammetry, and conformational and biochemical changes within the biofilm were studied using scanning electron microscopy (SEM) and Raman spectra.
PHOTODIAGNOSIS AND PHOTODYNAMIC THERAPY
(2023)
Article
Oncology
Azole Sindelo, Pinar Sen, Tebello Nyokong
Summary: Antimicrobial photodynamic inactivation (aPDI) is an effective method for eradicating drug-resistant microorganisms due to its minimal possibility of microbial resistance. This study focuses on the preparation and characterization of novel neutral and cationic morpholine containing Schiff base phthalocyanines. The cationic complexes show promising photodynamic activity against various microorganisms, while the neutral complexes are not suitable for antimicrobial studies. The effectiveness of aPDI is dependent on the concentration and light dose.
PHOTODIAGNOSIS AND PHOTODYNAMIC THERAPY
(2023)
Article
Chemistry, Inorganic & Nuclear
Reitumetse Nkhahle, Nthabeleng Molupe, John Mack, Tebello Nyokong
Summary: This work provides a synthesis method for an unsymmetrically substituted cobalt phthalocyanine and its symmetric counterpart, and applies them in electrocatalysis. The results show that the unsymmetrically substituted cobalt phthalocyanine exhibits superior performance in electrocatalytic reactions. The reactivity of the complexes is further evaluated using theoretical calculations, which indicate that the unsymmetrically substituted compound has higher reactivity.
INORGANICA CHIMICA ACTA
(2023)
Review
Chemistry, Inorganic & Nuclear
Balaji Babu, John Mack, Tebello Nyokong
Summary: Photodynamic therapy is a cancer treatment that involves a nontoxic photosensitizer, a light source, and ground-state molecular oxygen. Activation of the photosensitizer by light generates reactive oxygen species, which destroy cancer cells.
DALTON TRANSACTIONS
(2023)
Article
Engineering, Environmental
Shun-Shun Chen, Xu-Xiu Chen, Tian-Yu Yang, Li Chen, Zheng Guo, Xing-Jiu Huang
Summary: A temperature-modulated sensing strategy was proposed to identify and determine BTEX compounds. Highly effective identification of BTEX was achieved using linear discrimination and convolutional neural network analyses. Additionally, quantitative analysis of concentration was accomplished by establishing the relationship between concentration and response.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Myungkyung Noh, Jeong Yeon Sim, Jisung Kim, Jee Hwan Ahn, Hye-Young Min, Jong-Uk Lee, Jong-Sook Park, Ji Yun Jeong, Jae Young Lee, Shin Yup Lee, Hyo-Jong Lee, Choon-Sik Park, Ho-Young Lee
Summary: This study reveals that chronic exposure to PM induces chronic inflammation and development of COPD by dysregulating NAD+ metabolism and subsequent SIRT1 deficiency in pulmonary macrophages. Activation of SIRT1 by resveratrol effectively mitigates PM-induced inflammation and COPD development. Targeting metabolic and epigenetic reprogramming in macrophages induced by PM is a promising strategy for COPD treatment.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yu Liu, Linlin Qin, Yiming Qin, Tong Yang, Haoran Lu, Yulong Liu, Qiqi Zhang, Wenyan Liang
Summary: Co/NC/PAC electrode was prepared by compounding ZIF-67 with powder-activated carbon for the electrocatalytic treatment of nitrogen-containing heterocyclic compounds. The degradation efficiency of the four compounds reached 90.2-93.7% under optimal conditions, and the degradation order was pyridazine < pyrimidine < pyrazine < pyridine.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Julien Couturier, Pierre Tamba Oulare, Blanche Collin, Claire Lallemand, Isabelle Kieffer, Julien Longerey, Perrine Chaurand, Jerome Rose, Daniel Borschneck, Bernard Angeletti, Steven Criquet, Renaud Podor, Hamed Pourkhorsandi, Guilhem Arrachart, Clement Levard
Summary: This study analyzes the properties of bauxite residue samples and explores the influence of bauxite ore origin, storage conditions, and storage time. The results show that the speciation of yttrium is related to the origin of bauxite ore, while no significant variation was observed with storage conditions or aging of the residues.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Sakthinarenderan Saikumar, Ravi Mani, Mirunalini Ganesan, Inbakandan Dhinakarasamy, Thavamani Palanisami, Dharani Gopal
Summary: Microplastic contamination in marine ecosystems poses a growing concern due to its trophic transfer and negative effects on marine organisms. This study investigates the transfer and impacts of polystyrene microplastics in an estuarine food chain. The results show that microplastics can be transferred through the food chain, although the transfer rates are low. The exposed organisms exhibit stress responses, suggesting the potential risk of microplastics reaching humans through the food chain.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Review
Engineering, Environmental
Yan-Jiao Li, Ying Yuan, Wen-Bing Tan, Bei-Dou Xi, Hui Wang, Kun-Long Hui, Jia-Bao Chen, Yi-Fan Zhang, Lian-Feng Wang, Ren-Fei Li
Summary: This review investigated and analyzed the distribution, composition, and abundance of heavy metals and antibiotic resistance genes (ARGs) in landfill. The results showed that heavy metals have lasting effects on ARGs, and complexes of heavy metals and organic matter are common in landfill. This study provides a new basis to better understand the horizontal gene transfer (HGT) of ARGs in landfill.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Jessy Joseph, Ari Vaisanen, Ajay B. Patil, Manu Lahtinen
Summary: Efficient and environmentally friendly porous hybrid adsorbent beads have been developed for the removal of arsenic from drinking water. The structural tuning of the adsorbents has been shown to have a significant impact on their adsorption performance, with high crystallinity leading to increased adsorption capacity and selectivity towards As5+.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yangyang Liu, Minhua Xiao, Kaiqin Huang, Juntao Cui, Hongli Liu, Yingxin Yu, Shengtao Ma, Xihong Liu, Meiqing Lin
Summary: This study measured the levels of phthalate metabolites in breast milk collected from mothers in southern China. The results showed that phthalates are still prevalent in the region, and breastfeeding contributes to phthalate intake in infants. However, the levels detected do not pose significant health risks to infants based on dietary exposure. The increasing exposure to certain phthalates calls for further research into their sources and potential risks.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhiqiang Wu, Jianxing Sun, Liting Xu, Hongbo Zhou, Haina Cheng, Zhu Chen, Yuguang Wang, Jichao Yang
Summary: Ocean depth affects microbial diversity, composition, and co-occurrence patterns of microplastic microbial communities. Deterministic processes dominate the assembly of mesopelagic plastisphere microbial communities, while stochastic processes shape the assembly of bathypelagic microbial communities. The relationships between microorganisms in the mesopelagic layer are more complex and stable, with Proteobacteria and Actinobacteriota playing important roles.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Tingting Xiao, Renjie Chen, Chen Cai, Shijie Yuan, Xiaohu Dai, Bin Dong, Zuxin Xu
Summary: Based on the efficiency of catalytic ozonation techniques in enhancing sludge dewaterability, this study investigated its effectiveness in simultaneous reduction of antibiotics and antibiotic resistance genes. The results showed that catalytic ozonation conditioning changed the distribution of antibiotics and achieved high degradation rates. It also significantly reduced the abundance of ARGs, inhibited horizontal gene transfer, and decreased the signal transduction of typical ARGs host bacteria.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yang Deng, Xiaohong Guan
Summary: This article discusses two different development approaches for ferrate(VI) technology in water treatment, arguing that process integration is a promising method that can drive technological innovation and revolution in water treatment, achieving higher treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhe Zhang, Lu Zhang, Zhihao Huang, Yuxin Xu, Qingqing Zhao, Hongju Wang, Meiqing Shi, Xiangnan Li, Kai Jiang, Dapeng Wu
Summary: In this study, a floating catalytic foam was designed and prepared to enhance the mass transfer in immobilized photocatalysts for wastewater treatment. The floating catalytic foam could float on the water surface and establish a temperature gradient, effectively promoting the diffusion and adsorption of target molecules during the photocatalytic process.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Muhammad Nafees, Adiba Khan Sehrish, Sarah Owdah Alomrani, Linlin Qiu, Aasim Saeed, Shoaib Ahmad, Shafaqat Ali, Hongyan Guo
Summary: The accumulation of cadmium and antibiotics in edible plants and fertile soil is a worldwide problem. This study investigated the potential of zinc oxide nanoparticles to alleviate the toxicity of both cadmium and antibiotics and promote spinach growth.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Lurui Wan, Kai Wang, Yuan Chen, Zhiyong Xu, Wenbo Zhao
Summary: In this study, a low viscosity and high thermal stability SO2 absorbent with dual interacting sites was successfully synthesized. The absorbent showed the highest absorption enthalpy change and entropy change values among reported SO2 absorbents, and exhibited lower viscosity and comparable thermal stability to ILs.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhengwei Zhou, Guojie Ye, Yang Zong, Zhenyu Zhao, Deli Wu
Summary: This study utilized Mo powder and STPP to enhance the performance of the sodium percarbonate system in pollutant degradation. The presence of Mo and STPP resulted in a higher degradation rate of the model pollutant SMX, with low oxidant consumption. The system generated multiple active species through a series of chain reactions at different pH values, exhibiting excellent performance towards electron-rich pollutants. Furthermore, Mo demonstrated excellent stability and reusability.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
