4.6 Article

Tunable SrAl2Si2O8: Eu phosphor prepared in air via valence state-controlled means

Journal

OPTICAL MATERIALS
Volume 42, Issue -, Pages 80-86

Publisher

ELSEVIER
DOI: 10.1016/j.optmat.2014.12.023

Keywords

Tunable; SrAl2Si2O8; Eu; Phosphor; Luminescence

Funding

  1. National Natural Science Foundation of China [51472223]
  2. Fundamental Research Funds for the Central Universities [2012067]
  3. Program for New Century Excellent Talents in University of Ministry of Education of China [NCET-12-0951]

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SrAl2Si2O8: xEu (x = 0.5-8%) phosphors were prepared by the high-temperature solid-state reaction in air atmosphere. The phenomenon of Eu2+/Eu3+ coexistence was observed and the color of the SrAl2Si2O8: xEu phosphor could shift from light pink to blue by controllable and reproducible means. Photoluminescence (PL), excitation (PLE) spectra, X-ray photoelectron spectroscopy (XPS), and the fluorescence decay curves were employed to detect the presence of Eu2+ and Eu3+ ions in the compound. Under ultraviolet excitation, the broad band emission peaked at 410 nm originated from the transition of 4f(6)5d-4f(7) from Eu2+ and narrow band emissions peaked at 591 nm, 614 nm, 655 nm, and 703 nm are derived from the 4f-4f transition of Eu3+ ions, although the Eu3+ precursors were employed. The reduction mechanism from Eu3+ to Eu2+ in this compound was discussed in detail and verified by photoluminescence properties through changing the addition amount of Eu, temperature rise and holding time. (C) 2014 Elsevier B.V. All rights reserved.

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