Review
Chemistry, Physical
Wan Nabilah Manan, Wan Nor Roslam Wan Isahak, Zahira Yaakob
Summary: This paper reviews the management of CO2 emissions and the recent developments in bimetallic catalysts utilizing cerium oxide in dry reforming methane and steam reforming methane from 2015 to 2021. The focus is on the identification of key trends in catalyst preparation using cerium oxide and the effectiveness of the formulated catalysts.
Article
Chemistry, Applied
Shamil O. Omarov, Kirill D. Martinson, Anna N. Matveyeva, Maria Chebanenko, Vladimir N. Nevedomskiy, Vadim Popkov
Summary: Nanocrystalline Ni/CeO2 catalysts prepared by urea-nitrate combustion synthesis showed good catalytic performance in glycerol steam reforming. Characterization of the catalysts revealed that NiO mainly existed in the X-ray amorphous state and remained in the Ni-0 particles after reduction. Increasing the Ni content inhibited the agglomeration of CeO2 crystallites and increased the defectiveness of CeO2. The sample with 6.8 wt% Ni exhibited the best catalytic performance.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Ekaterina Smal, Yulia Bespalko, Marina Arapova, Valeria Fedorova, Konstantin Valeev, Nikita Eremeev, Ekaterina Sadovskaya, Tamara Krieger, Tatiana Glazneva, Vladislav Sadykov, Mikhail Simonov
Summary: A series of 5%Ni/Ce1-xTixO2 catalysts were prepared using nickel impregnation of mixed Ce-Ti oxides obtained via synthesis in supercritical isopropanol. The addition of Ti into the cubic fluorite phase structure increased the total reducibility of the catalysts and improved the interaction of supported Ni with the oxide support. The incorporation of Ti also prevented the detachment and sintering of Ni particles during dry reforming of methane.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
P. H. Tu, M. Sakamoto, K. Sasaki, Y. Shiratori
Summary: Using a two-step hydrothermal process, flowerlike Ce0.5Zr0.5O2 with high oxygen storage capacity was synthesized to prepare paper-structured catalysts. The catalysts exhibited excellent catalytic performance for dry reforming of methane due to the anti-sintering effect of Ni and the high oxygen storage capacity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yu-Shih Lin, Jia-Yun Tu, De-Hao Tsai
Summary: This study demonstrates a facile aerosol-based method to prepare hybrid nanostructures for catalyzing steam-promoted CO2 reforming with methane. The resulting NiPdOx-CeO2 nanoparticles deposited on SiO2 nanoparticle clusters exhibit superior catalytic performance at low temperatures, with high turnover frequency, tunable H2/CO ratio, and long-term operation stability. Incorporating SiO2 nanoparticle clusters as support material helps to enhance the dispersion of active metals and suppress metal sintering.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Agustin Salcedo, Pablo G. Lustemberg, Ning Rui, Robert M. Palomino, Zongyuan Liu, Slavomir Nemsak, Sanjaya D. Senanayake, Jose A. Rodriguez, M. Veronica Ganduglia-Pirovano, Beatriz Irigoyen
Summary: Ni/CeO2 catalysts show high activity for methane steam reforming at relatively low temperatures, effectively preventing coke formation, with hydroxyl-assisted CO formation providing a low-barrier pathway to prevent carbon accumulation.
Article
Thermodynamics
Dmitry Pashchenko, Anton Eremin
Summary: The numerical investigation of a steam methane reforming process focused on understanding the heat flows inside a catalyst particle. Results revealed irregular distribution of temperature field within the catalyst particle, with the lowest temperature occurring in the direction of flow.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2021)
Article
Chemistry, Multidisciplinary
Afshar Alipour-Dehkordi, Sajad Jabari Neek, Alireza Shahnazar
Summary: This study proposes a novel heat exchanger reactor for sustainable hydrogen production from glycerol steam reforming and investigates its performance using a mathematical model. The results demonstrate that this method has the potential to improve glycerol conversion and achieve energy savings.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Energy & Fuels
Azita Etminan, S. K. Sadrnezhaad
Summary: In this study, mesoporous monometallic and bimetallic catalysts were synthesized and characterized. The results showed that the bimetallic catalyst had higher conversion and lower carbon deposition in methane steam reforming. The study also suggested that highly dispersed active Ni species might play an important role in the catalyst activity and resistance to coking in the reaction.
Article
Nanoscience & Nanotechnology
Minsu Kim, Gihun Kwon, Wan-Gil Jung, Yunji Choi, Bong-Joong Kim, Hyunjoo Lee
Summary: Ex-solution from a ceria-based nanodomain is an effective method to prepare metal nanoparticle catalysts with a large surface area and excellent durability for gas-phase reactions at high temperatures. Rh nanoparticles ex-solved from Rh-doped ceria nanodomains showed high resistance against sintering and coke formation during the propane steam reforming process at 700 degrees C.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Fahad Maqbool, Syed Z. Abbas, Sergio Ramirez-Solis, Valerie Dupont, Tariq Mahmud
Summary: This study derived kinetic rates for 12 commonly used reforming catalysts based on conversion data obtained from literature, and studied the effects of variables such as temperature, pressure, S/C ratio, and G(s) on the performance of the SMR process. A comparative study was performed for the 12 catalysts, revealing that the choice of catalyst should depend on the operating conditions.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Pedro J. Megia, Anabel Morales, Arturo J. Vizcaino, Jose A. Calles, Alicia Carrero
Summary: By adjusting the O-2/AcOH molar ratio in the Ni/CeO2 catalyst, higher acetic acid conversion and hydrogen yield can be achieved with reduced coke deposition. The mesostructured Ni/CeO2 catalyst exhibits the best catalytic performance and the lowest coke formation.
Article
Engineering, Chemical
Yi Ran Lu, Petr A. Nikrityuk
Summary: This work presents a new 3D DEM-based model for steam reforming of methane in a tube filled with spherical catalyst particles. The model accurately predicts intraparticle and interparticle heat and mass transfer, showing good agreement with a 3D-CFD-based model.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Chemistry, Applied
R. P. Borges, L. G. Moura, S. Kanitkar, J. J. Spivey, F. B. Noronha, C. E. Hori
Summary: The study found that the silica molar content in Ni/CeO2-SiO2 catalyst significantly affects its performance, with higher silica content leading to larger surface area and smaller Ni crystallite size. Silica content also influences the metal-support interaction, ceria dispersion, and reducibility. Experimental results showed that Ni75CS catalyst performed the best during propane steam reforming.
Article
Chemistry, Physical
Israel R. Azevedo, Andressa A. A. da Silva, Yutao T. Xing, Raimundo C. Rabelo-Neto, Niels T. J. Luchters, Jack C. Q. Fletcher, Fabio B. Noronha, Lisiane V. Mattos
Summary: This study investigated the influence of dopants (Gd, Nb, Pr, and Zr) on the performance of Pt/CexMe1-xO2-g/Al2O3 catalysts for methane steam reforming. The results showed that dopants improved the reducibility and stability of the catalysts, with Nb-doped ceria demonstrating the highest stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Applied
Clement Maheu, Eric Puzenat, Pavel Afanasiev, Luis Cardenas, Christophe Geantet
Summary: This study investigated the influence of seven parameters on the photocatalytic production of hydrogen, including the optimal electron transfer from TiO2 to RuS2 at the rate-determining step. The photon yield showed an optimum at specific co-catalyst loading level, demonstrating the potential for optimizing electron transfer with incident photons having higher energy levels.
Article
Chemistry, Physical
Camila Daiane Ferreira da Silva, Fabien Claudel, Vincent Martin, Raphael Chattot, Sofyane Abbou, Kavita Kumar, Ignacio Jimenez-Morales, Sara Cavaliere, Deborah Jones, Jacques Roziere, Lluis Sola-Hernandez, Christian Beauger, Marco Faustini, Jennifer Peron, Bruno Gilles, Thierry Encinas, Laurent Piccolo, Fabio Henrique Barros de Lima, Laetitia Dubau, Frederic Maillard
Summary: Supported IrOx nanocatalysts are more active but less stable for OER compared to unsupported micrometer-sized catalysts, while Ta-doped tin oxides used as supports for IrOx nanoparticles show higher stability. Thermal annealing significantly reduces Ir atom dissolution rate for both micro- and nano-IrOx particles, leading to improved stability.
Review
Chemistry, Multidisciplinary
Zining Wang, Mingyue Liu, Fan Xiao, Georgeta Postole, Hongying Zhao, Guohua Zhao
Summary: Electrochemical advanced oxidation processes (EAOPs), particularly the heterogeneous electro-Fenton (EF) process, with in-situ formation of hydrogen peroxide (H2O2), have shown great potential for the effective and environmentally friendly treatment of refractory organic pollutants. This article discusses the surface catalytic mechanisms for H2O2 activation in the heterogeneous EF process and summarizes the required features for H2O2 formation via selective oxygen reduction reaction (ORR) with carbonaceous electrodes. It also provides an overview of solid Fenton catalysts and integrated functional cathodes used in heterogeneous EF for wastewater treatment, along with a brief discussion on their catalytic activity and stability under different experimental conditions. Additionally, the application of heterogeneous EF process in the remediation of emerging contaminants is highlighted, while emphasizing the challenges and future prospects related to catalytic fall-off and multi-step/complex techniques for water purification.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Applied
Sanja Bosnar, Vladislav Rac, Dusan Stosic, Arnaud Travert, Georgeta Postole, Aline Auroux, Sreco Skapin, Ljiljana Damjanovic-Vasilic, Josip Bronic, Xuesen Du, Smilja Markovic, Vladimir Pavlovic, Vesna Rakic
Summary: The dual templating approach attempted to synthesize hierarchical ZSM-5 zeolite using CTAB, resulting in phase separation in most synthesis routes, but a specific combination led to the formation of a homogeneous hierarchical ZSM-5 with flower-like morphology, possessing significant microporous and highly developed mesoporous surface.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Energy & Fuels
Quentin Touloumet, Lishil Silvester, Laurence Bois, Georgeta Postole, Aline Auroux
Summary: Composite materials based on AF and CaCl2 were developed for energy storage, with the salt content affecting the water sorption rate and heat of water sorption. Higher salt content led to better performance in terms of water absorption capacity and heat of sorption.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Chemistry, Physical
Daria Ryaboshapka, Laurent Piccolo, Mimoun Aouine, Pascal Bargiela, Valerie Briois, Pavel Afanasiev
Summary: In this study, ultradispersed molybdenum-based catalysts were successfully prepared by sulfidation of thiomolybdates and showed higher HDS activity than conventional MoS2 reference catalysts. Mixing with cobalt further increased the turnover frequencies, exceeding those of benchmark CoMoS catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Energy & Fuels
Quentin Touloumet, Georgeta Postole, Lishil Silvester, Laurence Bois, Aline Auroux
Summary: The study investigates the use of aluminum fumarate - porous alumina as a host matrix for CaCl2-based composite sorbents for thermochemical heat storage applications. The results show that the hierarchical porous structure impacts the physico-chemical characteristics and water storage performances, with enhanced capacity in the presence of micropores and mesoporosity. CaCl2-AF/Al composites exhibit increased water and heat storage capacities with higher salt content, reaching 1930 kJ kg(-1) and 0.68 kgH(2)O kg(-1) for 61 wt% of salt. The study highlights the significant impact of salt content on storage capacity and the influence of porosity on water vapor sorption behavior.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Daria Ryaboshapka, Pascal Bargiela, Laurent Piccolo, Pavel Afanasiev
Summary: MoS2-C3N4 composite materials were synthesized by one-pot synthesis method, and the solids were characterized by various physical techniques. The results showed that even at the lowest Mo content, the materials contained individual MoS2 and C3N4 phases. The composite materials exhibited excellent thiophene hydrodesulfurization activity and photocatalytic hydrogen evolution activity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Review
Chemistry, Physical
Jean-Luc Dubois, Georgeta Postole, Lishil Silvester, Aline Auroux
Summary: This article examines the selection criteria for isopropanol dehydration catalysts and analyzes the impact of process conditions and catalyst properties on propylene purity.
Article
Chemistry, Multidisciplinary
Leo Bossard-Giannesini, Luis Cardenas, Herve Cruguel, Aude Demessence, David Loffreda, Olivier Pluchery
Summary: Self-assembled monolayers composed of various long-chain aliphatic molecules and different tail functional groups have been synthesized and characterized on the Au(111) surface. The study shows that the chain length and tail group of the aliphatic molecules have a significant impact on the electronic properties of the self-assembled monolayers.
Article
Chemistry, Physical
Luis Cardenas, Clement Molinet-Chinaglia, Stephane Loridant
Summary: This study conducted a sequential analysis using UPS and XPS on ceria nanopowders to investigate the influence of X-ray beam on the oxide's surface. It was found, for the first time, that XPS analysis had a photoreductive effect on ceria after an oxidative pretreatment, leading to an overestimation of the Ce3+/Ce4+ ratio obtained by XPS. This spectroscopy methodology, particularly UPS, emerged as a leading technique for powder analysis with minimal impact on the authentic chemical state, facilitating the identification of the actual Ce4+ and Ce3+ ratio of ceria after oxidative and reductive in situ treatments.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
W. Liu, F. Morfin, K. Provost, M. Bahri, W. Baaziz, O. Ersen, L. Piccolo, C. Zlotea
Summary: Single-atom catalysts have attracted significant attention due to their unique catalytic properties. In this study, an Ir single-atom catalyst supported on a nitrogen-rich carbon substrate was prepared and found to exhibit substantial activity and high selectivity in the hydrogenation of butadiene. Quantitative operando X-ray absorption spectroscopy revealed that the initial Ir single atoms were coordinated with four light atoms and underwent partial reduction during pre-treatment.
Article
Chemistry, Multidisciplinary
Thomas Len, Mounib Bahri, Ovidiu Ersen, Yaya Lefkir, Luis Cardenas, Ignacio J. Villar-Garcia, Virginia Perez Dieste, Jordi Llorca, Noemie Perret, Ruben Checa, Eric Puzenat, Pavel Afanasiev, Franck Morfin, Laurent Piccolo
Summary: In Mo/TiO2 catalysts, the interaction between ultradispersed molybdate species and the support structure of rutile titanium nanorods plays a crucial role in achieving high activity and selectivity for methanol production.
Article
Chemistry, Physical
Wang Liu, Yann Magnin, Daniel Forster, Julie Bourgon, Thomas Len, Franck Morfin, Laurent Piccolo, Hakim Amara, Claudia Zlotea
Summary: In this study, hydrogen trapping in small Pd nanoparticles was explored through experimental and theoretical approaches. The results showed that the smaller the Pd particle size, the larger the amount of trapped hydrogen and the stronger the binding energy experienced by hydrogen atoms. The simulations indicated that the strong hydrogen trapping sites are octahedral interstitials located at the subsurface of Pd nanoparticles.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
