Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 146, Issue -, Pages 80-85Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2012.12.004
Keywords
Arenes; Benzyne; Insertions; 1,3-Dicarbonyl compounds; Fluorinated compounds
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The insertion of fluorinated 1,3-dicarbonyl compounds to benzyne resulted in regioselective formation of various fluorinated 1,5-dicarbonyl compounds which are not readily available by other methods. Products include 2-trifluoroacetyl- and 2-(perfluoroalkanoyl)phenylacetic estres, 2-fluoro-2-phenylacetic esters, 1-aryl-2-(2-trifluoroacetylphenyl)ethan-1-ones and other derivatives. (C) 2012 Elsevier B.V. All rights reserved.
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