Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 141, Issue -, Pages 49-57Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2012.06.005
Keywords
Perfluorinated compounds; Catalysis; Metathesis; Sphingo sine; Cytotoxicity
Categories
Funding
- Ministry of Education, Youth and Sports of the Czech Republic [Z40550506, MSM0021620857, LC06070, LC06077]
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Microwave induced cross-metathesis of perfluoroalkylated propenes with a substituted allyl alcohol is a simple and straightforward method for the synthesis of sphingosine derivatives possessing perfluoroalkyl chains. One of the prepared compounds was converted into the fluorinated clavaminol H derivative and its deacetylated congener. Selected compounds were subjected to preliminary testing for cytotoxic activity on several cancer cell lines. (C) 2012 Elsevier B.V. All rights reserved.
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