Journal
JOURNAL OF FLUORESCENCE
Volume 19, Issue 1, Pages 63-72Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10895-008-0381-7
Keywords
1-(4-Aminoantipyrine)-3-tosylurea; Rare earth (III) complex; Groove binding; Antioxidant activity
Funding
- National Natural Science Foundation in China [20171019]
- Zhide Foundation
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1-(4-Aminoantipyrine)-3-tosylurea (H2L) and its three lanthanide (III) complexes, M(H2L)(3) 3NO(3) [where M=Nd(III), Sm(III) and Eu(III)], have been synthesized and characterized. In addition, the DNA-binding properties of the three complexes have been investigated by UV-vis ( ultraviolet and visible) absorption spectroscopy, fluorescence spectroscopy, circular dichroism (CD) spectroscopy, cyclic voltammetry, and viscosity measurements. Results suggest that the three complexes bind to DNA via a groove binding mode. Furthermore, the antioxidant activity (superoxide and hydroxyl radical) of the metal complexes was determined by using spectrophotometer methods in vitro. These complexes were found to possess potent antioxidant activity and be better than standard antioxidants like vitamin C and mannitol.
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