Article
Chemistry, Applied
Xin Zhang, Fei Chen, Yuejin Li, Yongzheng Duan, Guoxia Liu
Summary: In this study, lanthanum-modified magnetic nanocomposites (La-SBA-15@Fe3O4-x) with Fe3O4 core and homogeneous mesoporous silica shell were prepared. The adsorption experiments showed that La-SBA-15@Fe3O4 had a good performance for removing phosphorus from aqueous solution. The materials were characterized by various techniques, and the results revealed the favorable morphology, composition and magnetic properties of the composites.
JOURNAL OF POROUS MATERIALS
(2022)
Article
Environmental Sciences
Zhiguo Lin, Jing Chen
Summary: By synthesizing magnetic composite material MMAL-0.375, this study effectively enhanced phosphate adsorption capacity and successfully applied it in wastewater treatment and sedimentary phosphorus control, achieving significant results.
Article
Environmental Sciences
Ali Dawood Salman, Tatjana Juzsakova, Redey Akos, Raheek I. Ibrahim, Mohammad A. Al-Mayyahi, Saja Mohsen, Thamer Adnan Abdullah, Endre Domokos
Summary: The main objective of this study is to produce an eco-friendly and economically nano-adsorbent for separating scandium metal ions from a model aqueous phase. The synthesized magnetic core-shell structure Fe3O4@SiO2 nanoparticles showed potential for industrial applications due to their easy removal and possibility of reuse. The ligand grafting on the nanoparticles did not significantly affect their morphology or structure, making them a promising option for separating rare earth elements from aqueous solutions.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Physical
Ramany Revathy, Nandakumar Kalarikkal, Manoj Raama Varma, Kuzhichalil Peethambharan Surendran
Summary: In this study, magnetoelectric composites of Fe3O4 and BaTiO3 were synthesized with 0-3 and 1-3 connectivity, showing the presence of exchange bias and an increasing trend of magnetoelectric coupling coefficients with higher BaTiO3 content in the investigated samples.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Environmental Sciences
Xiangcheng Shan, Yumeng Zhao, Shufeng Bo, Liyu Yang, Zuoyi Xiao, Qingda An, Shangru Zhai
Summary: A novel magnetic adsorbent AL-NH2@Fe3O4-Ce with high affinity for phosphate and excellent recyclability was developed for efficient phosphorus reclamation from wastewater. Batch experiments showed significantly higher phosphate adsorption capacity compared to aminated lignin and cerium oxide, indicating promising applications. Mechanisms of electrostatic attraction and inner-sphere complexation were proposed based on XPS analysis and batch experiments, showcasing the potential of AL-NH2@Fe3O4-Ce as a future adsorbent for phosphate removal processes.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Materials Science, Multidisciplinary
Yu-Cai Wu, Xi -Chun Zhong, Yuan-Xin Li, Xuan Huang, Jiao-Hong Huang, Cui-Lan Liu, Zhong-Wu Liu, Wan-Qi Qiu, Ming -Long Zhong, Zhen-Chen Zhong, R. V. Ramanujan
Summary: LaFe11.8Si1.2/16wt%La65Co35 samples were prepared by spark plasma sintering (SPS) and subsequent annealing. The La65Co35 binder increased the 1:13 phase content, and the alpha-Fe phase formed and disappeared during annealing. The sample annealed for 0.5 h showed a distinct core-shell structure, desirable table-like (-Delta S-M) -T curve, and higher RC value. The diffusion of Co was hindered by the growth of La5Si3 phase. Samples annealed for 24 h achieved larger (-Delta S-M)(max) and (sigma(bc))(max) values. The method combining SPS and diffusion annealing is promising for preparing La-Fe-Si based magnetocaloric composites with good properties.
MATERIALS RESEARCH BULLETIN
(2023)
Article
Chemistry, Multidisciplinary
Chi Zhang, Yao Wang, Yun Chen, Yatao Wang, Peng Wang, Qiong Wu
Summary: This paper investigates the synthesis of nanocomposites made of two kinds of magnetic nanoparticles using a special Co nanomatrix. The results show that embedding Fe3O4 nanoparticles into the branches of C-O clusters allows for close contact between the two types of particles and ensures optimal electromagnetic and magnetic properties.
Article
Materials Science, Ceramics
Miguel Fernandez-Ramos, Josefa Isasi, Mauricio Alcolea, Tamara Munoz-Ortiz, Elisa Ortiz-Rivero
Summary: This paper describes the preparation and study of new bifunctional samples (Y(0.9)Ln(0.1)VO(4)/Fe3O4)@SiO2 and [(Y(0.9)Ln(0.1)VO(4)@SiO2)/ Fe3O4@SiO2] with Ln = Nd or Tb. The influence of Fe3O4 content and silica coating on the Y(0.9)Ln(0.1)VO(4)@SiO2 samples is analyzed, and their potential utility is determined. These samples, which have potential applications in biomedicine, can be directed using an external magnetic field and allow the visualization of diseased cells. The experimental and theoretical studies provide insights into the structural and vibrational properties of the samples, confirming the presence of silica coating. The [(Y(0.9)Ln(0.1)VO(4)@SiO2)/Fe3O4@SiO2] samples show the most suitable properties for use as bifunctional materials.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Fenghao Zhang, Yahui Yan, Song Chen, Yajia Bai, Xiaona Li, Weiyi Chen, Aili Wei
Summary: In this study, chitosan/hydroxyapatite/Fe3O4 microspheres were synthesized using the water/oil emulsion technique. These microspheres exhibited excellent photothermal antibacterial properties and have the potential to be used as antibacterial biomaterials in biomedical applications.
Article
Engineering, Environmental
Xiaochang Lin, Yinglong Xie, Huijie Lu, Yicong Xin, Rubina Altaf, Songming Zhu, Dezhao Liu
Summary: Phosphate (P) is essential for the growth of all living organisms, and the depletion of minable P rock has led to an increasing demand for P recovery, driving the development of novel technologies. This study introduced a novel magnetic adsorbent, La-Zr@Fe3O4, for convenient and efficient P reclamation from wastewater or sludge, showing high affinity and rapid separation. The La-Zr@Fe3O4 demonstrated high stability and reusability in cyclic adsorption/desorption experiments, with potential for efficient phosphate sequestration and recovery.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Green & Sustainable Science & Technology
Rubina Altaf, Xiaochang Lin, Musa Abubakar Tadda, Songming Zhu, Dezhao Liu
Summary: A novel Zr-La@Fe3O4 adsorbent was developed for the removal and recovery of NTMP from wastewater, achieving 99% removal efficiency and high adsorption capacities. The Langmuir model and pseudo-second-order model were well demonstrated in the adsorption study, showing great potential for further research.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Green & Sustainable Science & Technology
Mingyao Yuan, Shangkai Qiu, Mengmeng Li, Zhao Di, Menghan Feng, Changbin Guo, Weilin Fu, Keqiang Zhang, Wenxian Hu, Feng Wang
Summary: In this study, the adsorption capacity of layered bimetallic hydroxide (LDH) for phosphate removal was enhanced by loading lanthanum (La) metal. The adsorption capacity of La-loaded LDH was 11.4% higher than that of normal LDH. The improvement in adsorption capacity was observed in a wide pH range (3-11) and in the presence of various coexisting ions. This study proposes a novel technique for enhancing LDH adsorption capability with potential applications in water treatment.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Polymer Science
Yao Lu, Xuna Jin, Xiang Li, Minpeng Liu, Baolei Liu, Xiaodan Zeng, Jie Chen, Zhigang Liu, Shihua Yu, Yucheng Xu
Summary: Superparamagnetic Fe3O4 particles were synthesized by solvothermal method, and a layer of dense silica sol polymer was coated on the surface prepared by sol-gel technique; then La(OH)(3) deposited on the surface of silica sol polymer by controlled in situ growth technology. These materials showed excellent adsorption capacity for phosphate removal, with a high removal rate, high sorption capacity, and good selectivity in the presence of competing ions. Moreover, the Fe3O4@La(OH)(3) particles demonstrated fast separability, easy reusability, and high stability.
Article
Chemistry, Physical
Le Jin, Jiqi Wang, Fei Wu, Yanan Yin, Baoliang Zhang
Summary: In this study, two MXene-based magnetic composites were innovatively fabricated and a high efficiency microwave absorbing system was obtained by blending these composites with the optimal ratio. The microwave absorbing mechanism mainly includes dielectric loss, magnetic loss, multiple reflection, and conductive loss.
Article
Chemistry, Physical
Xiaomin Kong, Runying Bai, Shuailin Wang, Bo Wu, Ruzhang Zhang, Huidong Li
Summary: The TiO2*/Fe3O4 composite prepared by sol-gel method shows excellent phosphate adsorption performance and can effectively adsorb and recover phosphate in wastewater treatment.
CHEMICAL PHYSICS LETTERS
(2022)