4.6 Article

Nanoporous alumino- and borosilicate-mediated Meinwald rearrangement of epoxides

Journal

APPLIED CATALYSIS A-GENERAL
Volume 493, Issue -, Pages 17-24

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2014.12.031

Keywords

Nanoporous silicates; Evaporation-induced self-assembly; Epoxides; Meinwald rearrangement; Heterogeneous catalysis

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Nanoporous alumina- and borosilicate materials, produced using an evaporation-induced self-assembly approach (EISA), efficiently catalyse the Meinwald rearrangement of epoxides in dimethyl carbonate (DMC) to produce the corresponding carbonyl compounds in high yield and excellent selectivity. (C) 2014 Elsevier B.V. All rights reserved.

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