4.7 Article

Degradation of pesticides chlorpyrifos, cypermethrin and chlorothalonil in aqueous solution by TiO2 photocatalysis

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 130, Issue -, Pages 160-165

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2013.08.058

Keywords

Chlorothalonil; Chlorpyrifos; Cypermethrin; Pesticide; Photocatalysis; UV/TiO2; UV/TiO2/H2O2

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Degradation of pesticides chlorpyrifos, cypermethrin and chlorothalonil in aqueous solution by TiO2 photocatalysis under UVA (365 nm) irradiation was examined. Enhancement of degradation and improvement in biodegradability index (BOD5/COD ratio) by H2O2 addition were also evaluated. UVA irradiation per se produced insignificant degradation of the pesticides. In UV/TiO2 photocatalysis (TiO2 1.5 g L-1, pH 6 and 300 mm irradiation), COD and TOC removal were 25.95 and 8.45%, respectively. In UV/TiO2/H2O2 photocatalysis (TiO2 1.5 g L-1, H2O2 100 mg L-1, pH 6 and 300 min irradiation), COD and TOC removal were 53.62 and 21.54%, respectively and biodegradability index improved to 0.26. Ammonianitrogen (NH3-N) decreased from 22 to 7.8 mg L-1 and nitrate-nitrogen (NO3--N) increased from 0.7 to 13.8 mg L-1 in 300 min, indicating mineralization. Photocatalytic degradation followed pseudo-first order kinetics with rate constant (k) of 0.0025 and 0.0008 min(-1) for COD and TOC removal, respectively. FTIR spectra indicated degradation of the organic bonds of the pesticides. UV/TiO2/H2O2 photocatalysis is effective in degradation of pesticides chlorpyrifos, cypermethrin and chlorothalonil in aqueous solution. UV/TiO2/H2O2 photocatalysis may be applied as pretreatment of a chlorpyrifos, cypermethrin and chlorothalonil pesticide wastewater at pH 6, for biological treatment. (C) 2013 Elsevier Ltd. All rights reserved.

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