4.7 Article

Extraction of phenanthrene and fluoranthene from contaminated sand using palm kernel and soybean oils

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 107, Issue -, Pages 124-130

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2012.04.029

Keywords

PAHs (polycyclic aromatic hydrocarbons); Soil remediation; Vegetable oil; Extraction

Funding

  1. Faculty of Engineering, The University of Nottingham Malaysia Campus
  2. Research Innovation Services, The University of Nottingham, United Kingdom [NRF4318]

Ask authors/readers for more resources

Experimental extraction tests are conducted to investigate feasibility of saturated palm kernel oil (PKO) and unsaturated soybean oil (SO) to extract polycyclic aromatic hydrocarbons (PAHs) from contaminated sand. The extraction rates and efficiencies for lowly contaminated (LC) and highly contaminated (HC) sands at temperatures of 30 degrees C and 70 degrees C are evaluated using empirical first order kinetic dissolution models. In LC sand, the extraction is dominated by the diffusion of PAHs adsorbed onto particle surfaces and the direct dissolution of PAH phase. In HC sand, a rapid diffusion of PAHs adsorbed onto particle surfaces and a direct dissolution of PAN phase occur followed by a slower diffusion of PAHs entrapped within the pores and micropores. Larger diffusion resistance during HC sand extractions results in an average 10.8% reduction in extraction efficiencies compared to LC sand. Increased temperature generally increases the mass transfer rates and extraction efficiencies. Additionally, the physicochemical properties of both oils and PAHs also determine the extent of PAN extraction into oil. (C) 2012 Elsevier Ltd. All rights reserved.

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