Article
Chemistry, Physical
Seongho Choi, Kazuya Kubo, Naoki Uchiyama, Tsunehiro Takeuchi
Summary: Thermoelectric properties of higher manganese silicide were investigated using a combination of ball milling and flash spark plasma sintering (FSPS) technique, and the results were compared to conventional spark plasma sintering (SPS) samples. Despite the short sintering time of less than 50 s, FSPS samples exhibited similar crystallographic and thermoelectric properties to SPS samples with much longer sintering time. Notably, the grain growth was significantly suppressed in the FSPS samples, although it had minor effects on the transport properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Saravanan Muthiah, Sushantika Choudhary, Priyanka Sangwan, Manju Yadav, Chandrakant Prajapati, Naval Kishor Upadhyay, Radhey Shyam, Sanjay R. Dhakate
Summary: Contact electrodes and their joining have been a major obstacle in achieving low-cost Mg2(Si,Sn) thermoelectric materials for thermoelectric generator applications. This study presents a facile single-step process to fabricate Sb-doped Mg2Si0.9Sn0.1 thermoelectric elements and contact joining simultaneously, effectively eliminating the main barrier in integrating Mg2(Si,Sn) materials in thermoelectric power generators.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
V. Cebotari, F. Popa, T. F. Marinca, B. V. Neamtu, N. A. Sechel, M. Galatanu, A. Galatanu, I. Chicinas
Summary: Mg2Si thermoelectric compound was successfully obtained by both dry and wet mechanical alloying methods. Wet milling with benzene resulted in smaller particle sizes and improved thermoelectric properties, including a higher Seebeck coefficient and lower electrical conductivity.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Multidisciplinary
Priyadarshini Balasubramanian, Manjusha Battabyal, Raghavan Gopalan
Summary: A modified sol-gel technique has been used to create an oxidation-resistant SiO2 coating on Mg2Si thermoelectric legs, improving their stability and oxidation resistance. The SiO2 coated Mg2Si maintains stable thermoelectric properties even after exposure to atmospheric conditions. This research offers a promising technique to prolong the lifespan of Mg2Si-based thermoelectric materials for waste heat recovery.
Article
Materials Science, Multidisciplinary
Tingting Chen, Jiyuan Wang, Xue Wang, Hongchao Wang, Wenbin Su, Jinze Zhai, Fahad Mehmood, Mahwish Khan, Chunlei Wang
Summary: In this study, ceramics with different scales of cross-scale pores were successfully designed and synthesized. The effects of pore structures on the performance of thermoelectric materials and uni-leg power generation modules were investigated. The results show that increasing pore size and porosity can significantly decrease thermal conductivity and improve thermoelectric properties.
APPLIED MATERIALS TODAY
(2022)
Article
Nanoscience & Nanotechnology
Stefano Boldrini, Alberto Ferrario, Stefano Fasolin, Alvise Miozzo, Simona Barison
Summary: Ultrafast high-temperature sintering (UHS) is a technique capable of synthesizing and sintering dense materials within seconds. This study presents a simple route to sinter Mg2Si pressed powders by UHS, which allowed for the production of dense samples with a total thermal history below 1 minute. The efficacy of the high process rate in preventing grain growth and avoiding significant Mg evaporation was demonstrated.
Article
Chemistry, Physical
Jie Chen, Wenhao Fan, Yachao Wang, Yu Jiang, Saneyuki Ohno, Zuhair A. Munir, Marhoun Ferhat, Shaoping Chen
Summary: This study examined the properties and stability of the interfaces between Mg2.05Si0.98Bi0.02 as a thermoelectric material and Ni and Mg50Si15Ni50 as barriers. The use of Mg50Si15Ni50 as a barrier resulted in a more stable interface without any evidence of interaction layer. In contrast, when Ni was used as a barrier, the interface was less stable. The efficiency and power output were higher when Mg50Si15Ni50 was used as a barrier.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
Nagendra S. Chauhan, Ichiro Ono, Kei Hayashi, Yuzuru Miyazaki
Summary: This study investigates the influence of the crystalline state on the thermal and electrical transport properties of a partially substituted manganese silicide alloy. The results demonstrate the efficacy of using rapidly solidified nanocrystalline polycrystals and secondary phases to enhance phonon scattering, as well as the effective carrier concentration and electrical conductivity improvement achieved through aliovalent aluminum substitution.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
W. Sun, R. Sui, G. Yuan, H. Zheng, Z. Zeng, P. Xie, Le Yuan, Z. Ren, F. Cai, Q. Zhang
Summary: In a traditional thermoelectric is-type module, severe thermal stress reduces lifespan, but a new design can reduce stress, enhance lifespan by 68%, and also improve output performance.
MATERIALS TODAY PHYSICS
(2021)
Article
Thermodynamics
Mingxin Bian, Zhiheng Xu, Caifeng Meng, Huanyu Zhao, Xiaobin Tang
Summary: This study proposes an optimized design and fabrication of the geometric configuration of thermoelectric legs to increase the power output of radioisotope thermoelectric generators in spacecraft. By increasing the heat dissipation on the side area, the performance enhancement principle is analyzed and applied. Special helix-shaped and spoke-shaped thermoelectric legs are fabricated using 3D printing technology. The analysis of the finite element method reveals that the helix-shaped legs and spoke-shaped legs can produce significantly higher power output compared to traditional cylinder-shaped legs. Integration of these special-shaped legs into the same space results in a higher power density due to lighter mass compared to traditional shapes. The simulation and experimental results confirm that the geometric design of thermoelectric legs with larger side areas can improve the output performance of thermoelectric devices.
APPLIED THERMAL ENGINEERING
(2022)
Article
Chemistry, Physical
Daishi Shiojiri, Tsutomu Iida, Hiroki Kakio, Masato Yamaguchi, Naomi Hirayama, Yoji Imai
Summary: Thermoelectric power generation using Mg2Si, doped with Sb and C, can enhance thermoelectric performance and effectively utilize waste heat energy.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Electrical & Electronic
Kunchit Singsoog, Athorn Vora-ud, Anek Charoenphakdee, Tosawat Seetawan
Summary: In this study, Ag/Bi codoped Mg2Si/MgO thermoelectric materials were successfully synthesized by ball milling and hot pressing. The Ag/Bi codoping was found to effectively reduce the electrical resistivity and enhance the power factor, with the codoped sample showing a significantly higher power factor than the undoped sample at room temperature.
JOURNAL OF ELECTRONIC MATERIALS
(2023)
Article
Engineering, Electrical & Electronic
Daishi Shiojiri, Tsutomu Iida, Hiroto Hamba, Takuya Kodama, Masato Yamaguchi, Naomi Hirayama, Yoji Imai
Summary: By optimizing carrier concentration and reducing thermal conductivity, we improved the thermoelectric performance of Mg2Si through the co-doping of antimony (Sb) and zinc (Zn). Experimental results showed that co-doping Sb and Zn increased the electrical conductivity of Mg2Si without significantly affecting its thermal conductivity, resulting in an improved dimensionless figure of merit.
JOURNAL OF ELECTRONIC MATERIALS
(2022)
Article
Thermodynamics
F. P. Brito, Rui Vieira, Jorge Martins, L. M. Goncalves, A. P. Goncalves, Rodrigo Coelho, E. B. Lopes, Elli Symeou, Theodora Kyratsi
Summary: The study evaluates the potential use of earth-abundant, affordable, non-toxic and performant TE materials in thermoelectric generators. Through experiments and simulations, it is found that there is a possibility to open the door to viable waste heat recovery in industrial and automotive applications.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Materials Science, Multidisciplinary
Jinzhao Zou, Shizhuan Xu, Jian Chen, Peng Wang, Chao Yan, Changqing Cao, Yan You, Junqiang Lu, Libing Zhu, Zhiyong Zhu, Jun Lin
Summary: In this study, U3Si2 pellets were successfully fabricated by spark plasma sintering (SPS) using U3Si2 clinkers generated by solid reaction between U and Si powders. The effects of SPS operating parameters on the microstructure of U3Si2 pellets were investigated. The results showed that increasing temperature and pressure enhanced the density of U3Si2 pellets, while low-temperature annealing effectively released the residual stress and eliminated the lattice distortion of U3Si2. The grain size of U3Si2 pellets increased with increasing dwell temperature, but showed an opposite trend with increasing pressure due to temperature-dependent surface diffusion and pressure-induced grain growth inhibition. The evolution of U3Si2 grain morphology from equiaxed to columnar grains was attributed to plastic strain under SPS conditions.
JOURNAL OF NUCLEAR MATERIALS
(2023)
Article
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Yutaka Taguchi, Takeshi Kutsuwa, Kiyohide Ichimi, Shinichi Kasatani
JOURNAL OF ELECTRONIC MATERIALS
(2016)
Article
Chemistry, Multidisciplinary
Tatsuya Sakamoto, Alessia Famengo, Simona Barison, Simone Battiston, Stefano Boldrini, Alberto Ferrario, Stefania Fiameni, Tsutomu Iida, Yoshifumi Takanashi, Monica Fabrizio
Article
Engineering, Electrical & Electronic
T. Nemoto, T. Iida, J. Sato, T. Sakamoto, T. Nakajima, Y. Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2012)
Article
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Tsutomu Iida, Yutaka Taguchi, Shota Kurosaki, Yusuke Hayatsu, Keishi Nishio, Yasuo Kogo, Yoshifumi Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2012)
Article
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Tsutomu Iida, Yasuhiko Honda, Mitsuhiro Tada, Takeshi Sekiguchi, Keishi Nishio, Yasuo Kogo, Yoshihumi Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2012)
Article
Engineering, Electrical & Electronic
Koya Arai, Masanori Matsubara, Yukie Sawada, Tatsuya Sakamoto, Tohru Kineri, Yasuo Kogo, Tsutomu Iida, Keishi Nishio
JOURNAL OF ELECTRONIC MATERIALS
(2012)
Article
Engineering, Electrical & Electronic
Takashi Nemoto, Tsutomu Iida, Junichi Sato, Tatsuya Sakamoto, Naomi Hirayama, Tadao Nakajima, Yoshihumi Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2013)
Article
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Tsutomu Iida, Yota Ohno, Masashi Ishikawa, Yasuo Kogo, Naomi Hirayama, Koya Arai, Takashi Nakamura, Keishi Nishio, Yoshifumi Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2014)
Article
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Tsutomu Iida, Takeshi Sekiguchi, Yutaka Taguchi, Naomi Hirayama, Keishi Nishio, Yoshifumi Takanashi
JOURNAL OF ELECTRONIC MATERIALS
(2014)
Article
Chemistry, Inorganic & Nuclear
Yusuke Hayatsu, Tsutomu Iida, Tatsuya Sakamoto, Shota Kurosaki, Keishi Nishio, Yasuo Kogo, Yoshifumi Takanashi
JOURNAL OF SOLID STATE CHEMISTRY
(2012)
Proceedings Paper
Materials Science, Multidisciplinary
A. Ferrario, S. Battiston, S. Boldrini, T. Sakamoto, E. Miorin, A. Famengo, A. Miozzo, S. Fiameni, T. Iida, M. Fabrizio
MATERIALS TODAY-PROCEEDINGS
(2015)
Proceedings Paper
Nanoscience & Nanotechnology
Y. Oto, T. Iida, T. Sakamoto, R. Miyahara, A. Natsui, K. Nishio, Y. Kogo, N. Hirayama, Y. Takanashi
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 10, NO 12
(2013)
Proceedings Paper
Engineering, Electrical & Electronic
Tatsuya Sakamoto, Kazuhiro Sugiyama, Daisuke Mori, Makoto Ogi, Keishi Nishio, Yasuo Kogo, Yoshifumi Takanashi, Tsutomu Iida
9TH EUROPEAN CONFERENCE ON THERMOELECTRICS (ECT2011)
(2012)
Proceedings Paper
Engineering, Electrical & Electronic
Keishi Nishio, Yukie Sawada, Koya Arai, Tatsuya Sakamoto, Yasuo Kogo, Tsutomu Iida
9TH EUROPEAN CONFERENCE ON THERMOELECTRICS (ECT2011)
(2012)
Proceedings Paper
Engineering, Electrical & Electronic
Yusuke Hayatsu, Tsutomu Iida, Tatsuya Sakamoto, Shota Kurosaki, Keishi Nishio, Yasuo Kogo, Yoshifumi Takanashi
9TH EUROPEAN CONFERENCE ON THERMOELECTRICS (ECT2011)
(2012)