Structure of the oxide film on Ti-6Ta alloy after immersion test in 8 mol/L boiling nitric acid medium

By using X-ray photoelectron spectroscopy (XPS), X-ray diffractometer (XRD) and scanning electron microscopy (SEM), we investigate the corrosion behavior and the structure of the oxide film of Ti-6Ta alloy that is subjected to the immersion corrosion test in 8 mol/L boiling nitric acid for 432 h. Based on the phase constitution indentified by depth profile XPS, the oxide film could be divided into three sub-layers along its thickness direction: the chemical stable TiO2 and Ta2O5 are present in layer I; the sub-oxide Ti2O3 and TaO are present in the layer II and layer III, and the high valence oxide evolutes from their sub-oxide gradually. Owing to the shielding effect of Ta2O5, the corrosion rate of the Ti-6Ta alloy decreases from 0.051 mm/y to 0.014 mm/y with increasing immersion time, showing an excellent corrosion resistance in 8 mol/L boiling nitric acid. (C) 2013 Elsevier B.V. All rights reserved.