Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 633, Issue 2, Pages 333-338Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2009.06.021
Keywords
Vanadium; Trace analysis; Chloranilic acid; Amalgam; Mercury film electrodes; Stripping voltammetry
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Funding
- Polish Ministry of Science and Education [15 020 02]
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The cyclic renewable mercury film silver based electrode (Hg(Ag)FE), applied for the determination of vanadium(V) traces using differential pulse adsorptive cathodic stripping voltammetry (DP AdCSV) with presence of chloranilic acid as a ligand is presented. The calibration graph obtained for V(V) is linear from 0.25 nM (12.7 ng L-1) to 150 nM (7.6 mu g L-1) for a preconcentration time of 20 s, with correlation coefficient of 0.9992. For a Hg(Ag)FE with a surface area of 6.6 mm(2) the detection limit for a preconcentration time of 90 s is as low as 0.5 ng L-1. The repeatability of the method at a concentration level of the analyte as low as 1.3 mu g L-1, expressed as RSD is 2.1% (n = 5). The proposed method was successfully applied and validated by studying the certified reference materials TMRAIN-95, SPS-SW1, SPS-SW2 and simultaneously recovery of V(V) from spiked water samples. (C) 2009 Elsevier B.V. All rights reserved.
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