Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 624, Issue 1-2, Pages 84-90Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2008.08.001
Keywords
Neutral nickel bisdithiolene complex; Cavity microelectrode; Electrochemical bandgap; Spectroelectrochemistry; Optical bandgap
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Funding
- ANR Solaire Photovoltaique French program
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The synthesis. spectroscopic and electrochemical characterizations of two neutral bisdithiolene nickel complexes are described. Electrochemical reversibility and bandgap have been measured by different techniques. The influence of the nature and length of the alkyl chain, the type of electrode (Pt microdisk for solutions, ITO-coated glass, Pt wire, and CME (cavity microelectrode) for condensed state) and the solvent have been investigated. Optical transmission measurements in the visible-near-IR (VIS-NIR) region allowed the determination of the optical bandgap. (C) 2008 Elsevier B.V. All rights reserved.
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