Relativistic and quantum electrodynamic effects in superheavy elements

The current status of relativistic electronic structure theory for superheavy elements is reviewed. Recent developments in relativistic quantum theory have made it possible to obtain accurate electronic properties for the trans-actinide elements with the aim to predict their chemical and physical behaviour. The role of quantum electrodynamic effects beyond the no-virtual-pair approximation, which is usually neglected in relativistic molecular calculations, is discussed. Changes in periodic trends due to relativistic effects are outlined for the superheavy elements with nuclear charge Z = 111-120. We also analyse the role of the negative energy states for the electronic stability of superheavy elements beyond the critical nuclear charge (Z(crit) approximate to 170), where the Is state enters the negative energy continuum at -2m(e)c(2). (C) 2015 Elsevier B.V. All rights reserved.