Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 67, Issue 7, Pages 1133-1140Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2014.910773
Keywords
Metal-organic framework; Nickel; Dinuclear building blocks; Magnetic property; Antibacterial activity
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Funding
- National Natural Science Foundation of China [21076041, 21276046]
- Ministry of Education, Science and Technology research project
- Fundamental Research Funds for the Central Universities of China
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A 2-D nickel(II) mixed-ligand metal-organic framework [Ni(NPTA)(4,4'-bipy)(H2O)](n) (1) was synthesized by reaction of 3-nitrophthalic acid (H(2)NPTA) and 4,4'-bipyridine (4,4'-bipy) with Ni(II) under hydrothermal condition and characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound 1 possesses a 2-D layer structure constructed from dinuclear nickel(II) building blocks in which two crystallographically equivalent Ni ions are bridged by two NPTA ligands. Furthermore, the layers are connected into 3-D supramolecular network by hydrogen bonds. The magnetism and antibacterial activity of 1 were investigated.
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