Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 66, Issue 3, Pages 464-472Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2012.761339
Keywords
Manganese(III) complex; Oxazine; Crystal structure; Olefin epoxidation; Sulfide oxidation
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Funding
- Research Council of University of Maragheh
- Sharif University of Technology
- National Science Foundation [CHE-0809901]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0809901] Funding Source: National Science Foundation
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A new manganese(III) complex [(NO)2Mn(OAc)] was synthesized using 2-(2-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (NO) as a bidentate O, N donor. The complex has been characterized by elemental analysis, IR, UVvis spectroscopy, and X-ray structure analysis. Oxidation of sulfides and epoxidation of olefins, respectively, to their corresponding sulfoxides and epoxides were conducted by this catalyst using urea hydrogen peroxide as oxidant at room temperature under air. The catalyst is efficient in oxidation reactions giving high yields and selectivities.
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