Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 65, Issue 22, Pages 3895-3902Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2012.728590
Keywords
Imidazole complexes; Crystal structure; UV-Vis spectrum; Magnetic properties; Fluorescence spectrum
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Funding
- Ministry of Education of the People's Republic of China [208034]
- Jilin Provincial Department of Education project [2009-203, 2011-192]
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[Ni-3(C13H9N2O)(5)(CH3OH)(2)] (1) and [Cd(C12H8N3)(3)] (2) were synthesized in methanol and characterized by elemental analyses, IR spectra, and X-ray diffraction. Complex 1 is trinuclear with three unsymmetric Ni(II)'s having different coordinated environments bridged by four oxygen atoms from five ligands. Intermolecular antiferromagnetic interactions were observed in 1. Complex 2 is mononuclear with Cd(II) six-coordinate by six nitrogen atoms from three bidentate HPBM anions. Complex 2 shows emission maxima in the blue region.
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