Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 63, Issue 2, Pages 307-314Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970903342117
Keywords
Quinoxaline-2-carboxaldehyde; 2-Amino-5-methylphenol; Crystal structure; Schiff base; Cobalt(II)
Categories
Funding
- Council of Scientific and Industrial Research, India
Ask authors/readers for more resources
The mononuclear cobalt(II) complex [CoL2]center dot H2O (where HL is quinoxaline-2-carboxalidine-2-amino-5-methylphenol) has been prepared and characterized by elemental analysis, conductivity measurement, IR, UV-Vis spectroscopy, TG-DTA, and X-ray structure determination. The crystallographic study shows that cobalt(II) is distorted octahedral with each tridentate NNO Schiff base in a cis arrangement. The crystal exhibits a 2-D polymeric structure parallel to [010] plane, formed by O-H center dot center dot center dot N and O-H center dot center dot center dot O intermolecular hydrogen bonds and pi-pi stacking interactions, as a racemic mixture of optical enantiomers. The ligand is a Schiff base derived from quinoxaline-2-carboxaldehyde.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available