Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 63, Issue 10, Pages 1785-1794Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2010.487938
Keywords
Coordination compound; Quinoxaline-2; 3-(1; 4H)-dithione; Quinoxaline-2; 3-(1; 4H)-dione; Isatin
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Funding
- Karnatak University, Dharwad
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Ligands derived from quinoxaline-2,3-(1,4H)-dithione are treated with Co(II), Ni(II), Cu(II), and Zn(II) chlorides to yield stable complexes. The prepared compounds are characterized by spectro-analytical techniques and magnetic susceptibility measurements, and the coordination behavior of ligands is discussed. All the complexes are octahedral and mononuclear with general formula [MLCl2(H2O)]. The electrochemical behavior of the synthesized compounds was investigated by cyclic voltammetry studies and the redox activity is explained.
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