Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 63, Issue 12, Pages 2172-2180Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2010.497553
Keywords
Quinoxaline; Quinoline; Coumarin; SNO donor system
Categories
Funding
- UGC
- Karnatak University
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A series of Co(II), Ni(II), Cu(II), and Zn(II) complexes of bi- and tridentate hydrazones were prepared. Ligands L1 and L2 were synthesized by the condensation of 2-mercapto-3-hydrazinoquinoxaline with 2-hydroxy-3-formylquinoline and 3-acetylcoumarin, respectively. The compounds were characterized by various spectro-analytical techniques and magnetic moment studies. The complexes are found to be monomeric and non-electrolytes. In these complexes, [CuL1Cl2] has square pyramidal geometry and others have octahedral. The copper complexes are electrochemically active in the applied potential range.
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