Journal
JOURNAL OF CLUSTER SCIENCE
Volume 22, Issue 4, Pages 587-601Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10876-011-0401-7
Keywords
Cobalt; Manganese; Phosphotungstates; Oxidation; Hydrogen peroxide
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Funding
- Council of Scientific and Industrial Research (CSIR, New Delhi)
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Keggin type Cobalt and Manganese substituted phosphotungstates were synthesized and characterized by various physicochemical techniques. They were efficiently used for liquid phase non-solvent oxidation of styrene under mild reaction conditions. It was found that the catalytic systems are efficient in achieving higher conversions with high turn over numbers (TONs) and are selective towards benzaldehyde (BA). The complexes behaved as homogeneous catalysts under present oxidation conditions and were efficiently regenerated after a simple workup and reused up to two cycles.
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