Article
Chemistry, Inorganic & Nuclear
Jia Yu, Linjuan Zheng, Li Zhang, Qinghui Mao, Weini Jia, Zhijie Liang
Summary: A new polyoxoniobate constructed by four {Nb-27} building blocks has been synthesized and characterized, showing potential as a precursor for functionalization. The structure, solution behavior, and characterization methods suggest the integrity and possibilities of this hybrid material.
JOURNAL OF COORDINATION CHEMISTRY
(2021)
Article
Chemistry, Physical
Shuai Wang, Yu Fei Wang, Zi Yang Wang, Chen Wang, Rong Huo, Jing Jin, Yong Heng Xing, Feng Ying Bai
Summary: Compound 1, polyoxoniobate {[Na-6(H2O)(14)][Nb6O19]}center dot 2H(3)O center dot H2O, was successfully synthesized in strong alkaline medium using the hydrothermal method. Its structure consists of polyoxoniobate anionic cluster and sodium water cluster, which allows for strong adsorption of cationic dyes.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Optics
Ruoxian Hou, Hanzhang Chen, Defu Sun, Nana Zhang, Chuanying Shen, Duanliang Wang
Summary: This research reports the synthesis, crystal structure, and optical properties of two new organic-inorganic hybrid materials. Transparent single crystals were successfully obtained using the solvent evaporation approach at room temperature. X-ray single crystal diffraction confirmed the layered structure of the crystals, with sulfamic acid and organics connected by hydrogen bonds. The optical properties of the crystals, including UV absorption and fluorescence spectra, were investigated, and the crystals exhibited low light absorption and distinct fluorescence characteristics.
Article
Chemistry, Physical
A. Kaiba, Mohammed H. Geesi, P. Guionneau, Yassine Riadi, Talal A. Aljohani, Ammar Elsanousi, Oussama Ouerghi
Summary: A new organic-inorganic hybrid material with a two-dimensional perovskite structure has been successfully synthesized and characterized using micro-Raman spectroscopy technique. The compound's structure was solved, showing a combination of [Cd-0.5 Cl-3](-) anions, organic +NH3(CH2)CO2H cations, and water molecules forming hydrogen-bonding network for cohesion.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Teresa Lee, Daniel B. Straus, Xianghan Xu, Weiwei Xie, Robert J. Cava
Summary: Magnetically active atomic distances can directly or indirectly impact the magnetic ordering in a given system. We synthesized three novel quasi-one-dimensional organic-inorganic hybrid cobalt chloride chain compounds and characterized their magnetic and thermodynamic properties. These compounds exhibit anti-ferromagnetic intrachain coupling and the strength of correlations is comparable across the three materials. The interchain Co-Co distance, which is determined by the size of the organic cation, is directly related to the temperature of long-range magnetic ordering.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Yan Luo, Yin-Qiang Zhang, Guan-Cheng Xu
Summary: In this study, a new displacement-type metal-free organic-inorganic hybrid phase transition material was successfully synthesized and its phase transition mechanism and structural changes were analyzed using single-crystal X-ray diffraction.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Wei-Bo Ren, Sai Sun, Zhixin Gao, Bo Li, Xinyu Chen, Qianqian Liu, Hong-Ying Zang
Summary: In this study, metal phosphovanadate materials with high proton conductivity were successfully synthesized by controlling the structure and enhancing stability. These materials exhibited good performance in terms of high temperature and long-term stability, providing a new approach for the development and design of porous proton-conducting materials.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Applied
Yin-Qiang Zhang, Min Li, Guan-Cheng Xu
Summary: An In-based organic-inorganic hybrid compound, [C3H8N](3)InBr6 (1; C3H8N+ is cyclopropylammonium), has been successfully synthesized and experienced a reversible phase transition at 298 K, as confirmed by DSC measurement. Single-crystal X-ray diffraction revealed different crystal structures at 330 K and 240 K, indicating a disorder-order changes of the cyclopropylammonium cations causing the structural phase transition, with an obvious dielectric anomaly near the transition temperature. This work paves the way for further exploration and design of In-based organic-inorganic hybrid phase transition materials.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Multidisciplinary Sciences
Liuyuan Han, Qian Wu, Longfei Lei, Jinghang Chen, Ni Xue
Summary: In this study, p-iodoaniline and p-phenylenediamine were introduced into Bi-based hybrid materials to prepare two photoactive iodobismuthates. Structural analysis and DFT calculations revealed specific structures and interactions in these materials. Photodetector experiments showed that the interaction provided by p-phenylenediamine has a positive effect on the optoelectronic properties of PIDBI.
Article
Chemistry, Inorganic & Nuclear
Ming Chen, Chang-Yuan Su, Wan-Ying Zhang, Wei-Yi Wang, Pei-Zhi Huang, Yi Zhang, Da-Wei Fu
Summary: The study focused on hybrid switchable materials induced by dielectric phase transition, revealing that flexible organic cations are more likely to undergo dynamic motion under temperature stimulation. A new organic-inorganic hybrid crystal was successfully designed, showing reversible phase transition and significant dielectric response with excellent cycle stability. The report of this compound is believed to be conducive to the design of new series of switching materials.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Haruka Ikuma, Shunsuke Aoki, Kai Kawahara, Seiji Ono, Hironori Iwamatsu, Jun Kobayashi, Yoshiki Kiyota, Yosuke Okamura, Masashi Higuchi, Takeru Ito
Summary: Surfactants are functional molecules that can form nanometer-sized architectures. Bolaamphiphile surfactants with two hydrophilic heads are effective in constructing inorganic-organic hybrids. In this study, a hybrid crystal consisting of polyoxotungstate and a bolaamphiphile was successfully formed.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Fafa Wu, Qingyin Wei, Xiaoqi Li, Yi Liu, Weiqi Huang, Qin Chen, Bingxuan Li, Junhua Luo, Xitao Liu
Summary: Exploration of nonlinear optical crystalline materials is a hot topic in the field of modern optoelectronics and laser technology. The study focuses on the emerging organic-inorganic hybrid metal halides, which have the potential to provide infinite opportunities. In this study, a non-centrosymmetric organic-inorganic hybrid antimony halide was developed by combining an inorganic second-order Jahn-Teller distorted octahedron with an organic pi-conjugated aromatic amine. The crystals showed a remarkable second harmonic generation response and moderate birefringence, indicating their potential for applications in the field of nonlinear optics. The crystal structure analysis and theoretical calculations revealed that the large second harmonic generation response is primarily due to the cooperative coupling between the highly asymmetric distorted octahedron and the pi-conjugated aromatic amine.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Tasnim Rahman, Enric Petrus, Mireia Segado, Nicolas P. Martin, Lauren N. Palys, Mark A. Rambaran, C. Andre Ohlin, Carles Bo, May Nyman
Summary: Anomalous solubility behavior of alkali-POMs has been discovered and successfully predicted using computation and simulation, providing guidelines for the discovery of new POMs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Materials Science, Multidisciplinary
Takashi Doi, Tsutomu Shimokawa
Summary: This paper presents the development of an organic-inorganic hybrid thermoset-based dual tone-type photosensitive material, which can form both positive and negative patterns by changing the patterning process. The solubility of the material was controlled by three factors: copolymer composition, polymer composition contents, and process conditions. The solubility changes were confirmed by various analyses. Thin coating films on silicon wafers showed good adhesion and heat resistance. This material is expected to be used in the production of permanent film materials for high-density semiconductor packages.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Taiki Nishimura, Satoshi Katsuhara, Chaehun Lee, Brian J. Ree, Redouane Borsali, Takuya Yamamoto, Kenji Tajima, Toshifumi Satoh, Takuya Isono
Summary: This study introduces a novel block copolymer system by utilizing carbohydrates and inorganic hybrids, synthesized through click reactions. The block copolymers demonstrated various microphase-separated structures in both bulk and thin film states, with potential for nanopatterning applications after reactive ion etching.
