Journal
NEW JOURNAL OF CHEMISTRY
Volume 39, Issue 5, Pages 3758-3764Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4nj02402h
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Funding
- CSIR [01(2516)/11/EMR-II]
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A simple route has been established for grafting molybdenum carbonyl onto the surface of a diaminosilane-modified SBA-15 molecular sieve. The successful grafting of the molybdenum carbonyl species onto diamine-functionalized SBA-15 was evident from FT-IR studies. The resultant molybdenum-carbonyl-complex-grafted SBA-15 (SBA-DA-Mo) materials show promising activity for the epoxidation of various olefins with good conversion (90-95%) and the formation of epoxide as the major product. The catalytic activity remains constant over several runs.
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