Journal
JOURNAL OF CHROMATOGRAPHY A
Volume 1177, Issue 1, Pages 92-104Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.chroma.2007.11.009
Keywords
axial temperature profiles; column efficiency; heat generation; heat transfer; radial temperature profiles; viscous friction
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The combination of the heat balance in a chromatographic column percolated by a stream of mobile phase and of the model of band migration under linear conditions along such a column permits the calculation of the axial and radial temperature distributions in the column, of the elution band profiles, and of the column efficiency under different sets of experimental conditions. The calculated results are always consistent with the experimental results published by different groups and often in good quantitative agreement. Minor discrepancies arise from difficulties in deriving precise estimates of the heat transfers from the column due to the massive endfittings of the column and to uncontrolled heat transfer from the column tube to ambient air. (C) 2007 Elsevier B.V. All rights reserved.
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