Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 59, Issue -, Pages 121-126Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2012.12.011
Keywords
2-Amino-2-hydroxymethyl-1,3-propanediol; Diethylene glycol; Tetraethylene glycol; Thermophysical property characterization; Triethylene glycol
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Funding
- Mapua Institute of Technology
- Chung Yuan Christian University
- National Science Council of the Republic of China [NSC 99-2221-E-033-044-MY3]
- DOST-Philippines through NAST-OYS
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As part of our systematic study on physicochemical characterization of (glycol + amine) systems, thermophysical properties, including refractive index, density, and electrolytic conductivity measurements were carried out on aqueous systems containing glycol and 2-amino-2-hydroxymethyl-1,3-propanediol (TRIS). The glycols studied are diethylene glycol (DEG), triethylene glycol (TEG), and tetraethylene glycol (T(4)EG). The measurements were done over a temperature range of (298.15 to 343.15) K at normal atmospheric pressure. Different concentrations (4 to 16)% by weight TRIS or (56 to 44)% water, in a fixed amount 40% glycol were used. The influences of temperature and compositions on the measured properties are discussed and then correlated based on the equation proposed for aqueous (glycol + salt) systems. Calculated results show that the applied model is satisfactory in representing the measured properties in the aqueous systems containing the glycols and TRIS. (C) 2013 Elsevier Ltd. All rights reserved.
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