Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 43, Issue 12, Pages 1810-1817Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2011.06.007
Keywords
[BMPYR][TCB]; Activity coefficients at infinite dilution; Thermodynamics; Density; The Abraham solvation parameter model
Categories
Funding
- Warsaw University of Technology
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The activity coefficients at infinite dilution, y(13)(proportional to), for 45 solutes, including alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, thiophene, tetrahydrofuran, ethers, acetone, and water, in the ionic liquid 1-butyl-1-methylpyrrolidinium tetracyanoborate, [BMPYR][TCB], were determined by gas-liquid chromatography at temperatures from 318.15 K to 368.15 K. The values of the partial molar excess Gibbs free energy Delta G(1)(E,infinity) enthalpy Delta H-1(E,infinity) and entropy Delta S-1(E,infinity) at infinite dilution were calculated from the experimental gamma(infinity)(13) values obtained over the temperature range. The gas-liquid partition coefficients, K-L were calculated for all solutes and the Abraham solvation parameter model was discussed. The values of the selectivity for different separation problems were calculated from gamma(infinity)(13) and compared to literature values for N-methyl-2-pyrrolidinone (NMP), sulfolane, 1-ethyl-3-methylimidazolium tetracyanoborate, [EMIM][TCB], 1-decyl-3-methylimidazolium tetracyanoborate, [DMIM][TCB], and similar ionic liquids. The densities of [BMPYR][TCB] in temperatures range from 318.15 K to 368.15 K, the temperature of fusion and the enthalpy of fusion were measured. (C) 2011 Elsevier Ltd. All rights reserved.
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