Journal
JOURNAL OF CHEMICAL EDUCATION
Volume 91, Issue 12, Pages 2186-2190Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ed4005062
Keywords
Upper-Division Undergraduate; Physical Chemistry; Hands-On Learning/Manipulatives; UV-vis Spectroscopy; Raman Spectroscopy; Computational Chemistry; Nanotechnology; Laboratory Instruction
Funding
- U.S. National Science Foundation [EPS-0903787, NSF-0955550]
- University of Mississippi College of Liberal Arts, Department of Chemistry and Biochemistry, Office of Research and Sponsored Programs
- Sally McDonnell Barksdale Honors College
- NSF [CHE-1156713]
- Office of Science, U.S. Department of Energy [DE-FG02-04ER15514]
- U.S. Department of Energy (DOE) [DE-FG02-04ER15514] Funding Source: U.S. Department of Energy (DOE)
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0955550] Funding Source: National Science Foundation
- EPSCoR
- Office Of The Director [0903787] Funding Source: National Science Foundation
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This laboratory exercise introduces undergraduate chemistry majors to the spectroscopic and theoretical study of the polycyclic aromatic hydrocarbon (PAR), corannulene. Students explore the spectroscopic properties of corannulene using UV-vis and Raman vibrational spectroscopies. They compare their experimental results to simulated vibrational spectra and the molecular structure obtained from computational chemistry to other PAHs, including C-60. The delocalized electron in corannulene is also conceptually explored using the particle in a disk model. This laboratory exercise allows students to explore multiple physical chemistry concepts in one, 3 h laboratory exercise centered around one theme.
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