4.2 Article

Dissociation Constants and Thermodynamic Properties of Amines and Alkanolamines from (293 to 353) K

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 54, Issue 4, Pages 1318-1328

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/je800897v

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Funding

  1. Dutch government (EOS)
  2. consortium partners

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The dissociation constants of protonated 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, diethylmonoethanolamine, diisopropanolamine, dimethylmonoethanolamine, monoethanolamine, 1-amino-2-propanol, methylmonoethanolamine, triethanolamine, and the first and the second dissociation constants of piperazine and hydroxyethylpiperazine have been determined by electromotive force measurements from (293 to 353) K. The dissociation constants of protonated triethylamine have been determined with the same technique from (293 to 333) K. The experimental results and derived values of the standard state thermodynamic properties are reported and compared to available literature values.

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