Journal
JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 53, Issue 12, Pages 2833-2837Publisher
AMER CHEMICAL SOC
DOI: 10.1021/je800566y
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Funding
- Korea Evaluation Institute of Industrial Technology (KEIT) [2007-M-CC22-P-02-0-000] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Korea Institute of Industrial Technology(KITECH) [2007-M-CC22-P-02] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Hydrate phase equilibria have been measured for carbon dioxide + cyclic ethers + water in the temperature range of (270 to 290) K and in the pressure range of (0.2 to 4.7) MPa. Three cyclic ethers, THF, propylene oxide, and 1,4-dioxane, were selected at a mole fraction of 0.03. The stabilization effect of the mixed hydrate was found to be the highest for THF followed by propylene oxide, while no stabilization effect was observed for 1,4-dioxane in the studied temperature and pressure range. The mole fraction effect on hydrate phase equilibria has also been investigated for THF and propylene oxide in the range of x = (0.01 to 0.10).
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