Article
Materials Science, Multidisciplinary
Yin Yam Chan, Andreas Korwitz, Doris Pospiech, Bernhard Schartel
Summary: A series of flexible polyurethane foams (FPUFs) were prepared with different combinations of flame retardants and additives to evaluate their synergistic effects on the properties of FPUFs. It was found that the combination of expandable graphite and phosphorous polyol significantly improved the char yield of the foams, thereby enhancing their flame retardancy. Furthermore, the addition of expandable graphite effectively reduced smoke and toxic gas emissions, while the replacement of polyether polyol with castor oil maintained the physical and mechanical properties and improved the bio-based content.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Polymer Science
Yin Yam Chan, Chao Ma, Feng Zhou, Yuan Hu, Bernhard Schartel
Summary: An alternative phosphorous soybean-oil-based polyol was used for flexible polyurethane foams synthesis, with the addition of 5% and 10% expandable graphite (EG) to improve flame retardancy. The combination of phosphorous polyols and EG showed significantly enhanced flame retardancy, with a three times increase in char yield, indicating a potential strategy for future flame retarded FPUFs.
POLYMER DEGRADATION AND STABILITY
(2021)
Article
Polymer Science
Yin Yam Chan, Chao Ma, Feng Zhou, Yuan Hu, Bernhard Schartel
Summary: A series of flexible polyurethane foams with different concentrations of flame retardants, bis([dimethoxyphosphoryl]methyl) phenyl phosphate (BDMPP), and either melamine (MA) or expandable graphite (EG) were prepared and studied. The synergistic effect of BDMPP and EG on flame retardancy was highlighted, with EG showing excellent smoke suppression during burning and MA significantly reducing the peak heat release rate. The combination of BDMPP and EG, along with MA, offers an approach to enhance flame retardancy and smoke suppression.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2022)
Article
Polymer Science
Jin Kim, Sang-Bum Kim
Summary: In order to improve the flame retardancy of rigid polyurethane foam, different particle sizes and expansion rates of expandable graphite were added. Urethane and isocyanurate ring were confirmed using Fourier Transform Infrared Spectroscopy (FTIR), and the heat resistance of the foam was analyzed through Thermogravimetric Analysis (TGA). The effect of expandable graphite on the mechanical properties was confirmed by measuring the compressive strength, while the flame retardancy was analyzed through UL94 V test, Limited Oxygen Index (LOI), and measurement of weight loss due to combustion.
Article
Chemistry, Multidisciplinary
D. Meng, Y. Li, P. Qi, J. Sun, X. Gu, H. Li, Z. Wang, S. Zhang
Summary: Flexible polyurethane foam (FPUF) often requires flame retardants to enhance fire resistance. This study developed a bio-based coating by depositing polydopamine and guanosine 5'-monophosphate disodium salt (GMP) to improve the fire safety of FPUF. The coating significantly increased flame retardancy, reduced heat and smoke release, and improved compressive strength.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Engineering, Manufacturing
Shenghe Zhang, Fukai Chu, Yifan Zhou, Zhoumei Xu, Xin Jiang, Xiaoyu Luo, Guojie Yuan, Yuan Hu, Weizhao Hu
Summary: In this paper, flexible polyurethane (PU) was successfully prepared by introducing diphenylphosphinyl chloride and 3-aminopropyltriethoxysilane (KH550) into castor oil. The modified PU showed excellent flame-retardant and smoke-suppressing effects, and it was able to rapidly absorb organic solvents. The modified foam also met certain mechanical properties. This work broadens the thinking for the preparation of high-performance flexible PU materials with green intrinsic fire-retardancy.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Polymer Science
Wei Lu, Zhipeng Zeng, Zhenglong He, Yuntao Liang, Yong Sun, Shuanglin Song, Lili Wang, Ruling Liu
Summary: A highly dispersed melamine/red phosphorus (MA/RP) composite flame retardant was prepared through mechanical grinding, which effectively dispersed RP in the substrate and improved its flame retardancy. MA/RP flame retardant was then used to prepare organic-inorganic hybrid foams (MA/RP/HF) with uniform and closed pores. The resulting MA/RP/HF showed good thermal stability and achieved the V-0 grade in flame retardant tests, demonstrating its superior flame retardancy compared to rigid polyurethane-based foam and pure HF. The study also discussed the synergistic flame retardancy mechanism of MA and RP on polyurethane-based foam.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Edgar H. H. Wong, Ka Wai Fan, Lei Lei, Cheng Wang, Juan Carlos Baena, Henry Okoye, Winny Fam, Dewen Zhou, Susan Oliver, Arslan Khalid, Guan Heng Yeoh, Chun H. Wang, Cyrille Boyer
Summary: A new method using halogen-free nature-inspired coatings to fabricate highly fire-resistant flexible PUF has been developed in this study, which is environmentally friendly and sustainable. The coatings offer excellent flame-retardant properties and could potentially meet the highest global industry standard.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Physics, Condensed Matter
Xin-Chao Wang, Ya-Peng Sun, Jie Sheng, Tie Geng, Lih-Sheng Turng, Yong-Gang Guo, Xian-Hu Liu, Chun-Tai Liu
Summary: This study incorporated expansible graphite (EG) as a flame retardant into polyurethane foams (PUFs) to improve their fire resistance. The addition of EG reduced bubble size and increased mass density in PUFs, while maintaining their functional group structures. Such addition also enhanced thermal stability and flame retardancy without significantly compromising compression strength. These findings provide useful guidelines for the industrial production and applications of PUFs.
JOURNAL OF PHYSICS-CONDENSED MATTER
(2022)
Article
Polymer Science
Huhu Zhou, Shuai Tan, Caihong Wang, Yong Wu
Summary: By synthesizing and incorporating a room temperature ionic liquid, TPT, containing phosphorus and sulfur elements into flexible polyurethane foam at a low dosage, enhanced flame retardancy can be achieved without compromising thermal stability and mechanical performance. The use of TPT in FPUF significantly reduces peak heat release rate and increases oxygen index value.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Polymer Science
Xiping Gao, Dongxue Li, Min Lu, Dahu Yao, Chang Lu
Summary: Fire detection sensors are necessary for fire safety, but long response times and false alarms are urgent problems. This study used a strategy of embedding expandable graphite in a polymer/flame retardant sample to enable multiple modes of fire detection and early warning functions, shortening response time and preventing false alarms. The study showed potential application for rapid fire warning in buildings.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2023)
Article
Chemistry, Applied
Xiaochen Dong, Xuefan Yang, Shitong Liang, Jiaqi Li, Kesong Wang, Jichun Liu, Haibo Chang
Summary: Polypropylene was modified with expandable graphite and magnesium hydroxide to improve its flame retardancy. The influence of expandable graphite particle size on the fire behavior of PP/MH/EG ternary composite was investigated. The findings indicate that expandable graphite has a strong synergistic effect with magnesium hydroxide in flame-retarding polypropylene. The composite with larger expandable graphite particle size demonstrates better flame retardancy, smoke inhibition, acid resistivity, processability, and lower toxic gas release during combustion.
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
(2023)
Article
Polymer Science
Yao Chen, Zhuyu Bai, Xiaoyu Xu, Jianbing Guo, Xiaolang Chen, Shaw Ling Hsu, Zongcheng Lu, Hong Wu
Summary: Researchers have developed a hybrid expandable graphite (EG) intumescent flame retardant for improving the fire safety of rigid polyurethane foam (RPUF). The flame-retardant properties of RPUF composites with Hexachlorocyclotriphosphazene (HCCP) self-assembled on the surface and interlamination of EG (HCCP@EG) were significantly enhanced, achieving a UL-94 V-0 level and a limiting index higher than 27.0%. The presence of HCCP also improved the mechanical property of RPUF composites through enhancing the interface compatibility between EG and RPUF.
Article
Materials Science, Multidisciplinary
Mengru Liu, Haifeng Shen, Yuzhou Luo, Renhui Zhang, Yi Tao, Xiuyu Liu, Zhifang Zong, Gang Tang
Summary: In this research, piperazine pyrophosphate (PAPP) and expandable graphite (EG) were added to improve the fire performance of RPUF. The addition of flame retardants reduced the peak heat release rate (PHRR) and total heat release (THR), further improving the fire performance of the compounds. The formation of a denser char residue and significant improvement in the graphitization degree due to the PAPP/EG synergistic effect contributed to the improved fire resistance.
FIRE AND MATERIALS
(2023)
Article
Polymer Science
Hongkun Wang, Qiang Liu, Hui Li, Hao Zhang, Shouke Yan
Summary: In this study, a liquid-phosphorus-containing polyester diol (PPE) was incorporated into flame-retardant polyester-based flexible polyurethane foams (P-FPUFs). The results showed that PPE increased the flexibility of the foams and reduced the heat release rate and total heat release. Furthermore, the addition of expandable graphite (EG) further decreased the smoke production and increased the char formation.