Article
Chemistry, Physical
Xianfang Yi, Jinxiu Wang, Yuqiu Liu, Yanting Chen, Jinsheng Chen
Summary: This study developed a FeCeVWTi catalyst by modifying V2O5-WO3/TiO2 with FeOx and CeOx. The FeCeVWTi catalyst exhibited excellent SCR activity, resistance to alkali and heavy metals, as well as tolerance to H2O and SO2. The co-doping of Fe and Ce significantly improved the redox ability and NOx adsorption of the catalyst.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Geochemistry & Geophysics
Zhanwei He, Xiaojun Hu, Mo Lan, Jianxing Liu, Gongjin Cheng, Xiangxin Xue, Kouchih Chou
Summary: Different types of vanadia-titania magnetite (VTM) have varying reduction and softening-melting-dripping properties in a blast furnace, with an increase in TiO2 content negatively impacting performance. It is recommended to smelt high TiO2 VTM mixed with ordinary ores or with an increased pellet ratio in the burden structure to counteract the adverse effect on softening-melting-dripping properties.
Article
Chemistry, Inorganic & Nuclear
Sateesh Mulkapuri, Athira Ravi, Subhabrata Mukhopadhyay, Sathish Kumar Kurapati, Vinaya Siby, Samar K. Das
Summary: Grafting a W-VI-(OH)(2) functionality onto the surface of polyoxometalates (POMs) produces heterogeneous electrocatalysts for water reduction to molecular hydrogen. The W-VI(OH)(2) functionality is identified as the active site for electrocatalytic hydrogen evolution reaction (HER). Controlled experiments eliminate the generation and participation of secondary species. The electrocatalysts 1 and 2 exhibit high stability and efficiency towards electrocatalytic HER. This work has the potential to generalize the use of POMs with M-OH functionality as catalysts for HER.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Materials Science, Multidisciplinary
Zhenxing Xing, Gongjin Cheng, Zixian Gao, He Yang, Xiangxin Xue
Summary: This study investigates the impact of New Zealand sea sand ore on the performance and metallurgical properties of green and oxidized pellets. The inclusion of sea sand ore as a raw material can potentially reduce production costs for iron and steel enterprises, although excessive usage may decrease reduction efficiency.
Article
Chemistry, Analytical
Yujiao Bai, Jiansong Miao, Xiaodi Bian, Qian Wang, Wenqing Gao, Yu Xue, Guihua Yang, Peihua Zhu, Jinghua Yu
Summary: MWCNTs@COF-366-Co was prepared by growing a cobalt porphyrin-based covalent organic framework (COF-366-Co) on multi-walled carbon nanotubes (MWCNTs), and a unique biosensing platform for ultrasensitive real-time NO determination was established. The MWCNTs@COF-366-Co electrochemical biosensor exhibited excellent NO determination performance in a wide range, with high sensitivity and a low limit of detection. Additionally, it was successfully used to monitor NO molecules released from human umbilical vein endothelial cells (HUVECs).
Article
Multidisciplinary Sciences
Inhak Song, Hwangho Lee, Se Won Jeon, Ismail A. M. Ibrahim, Joonwoo Kim, Youngchul Byun, Dong Jun Koh, Jeong Woo Han, Do Heui Kim
Summary: This study demonstrates that physically mixed H-Y zeolite can protect vanadium active sites effectively by trapping ABS in micropores, enabling the catalyst to operate stably at low temperatures and maintaining sulfur resistance during repeated aging/regeneration cycles. The pore structure and framework Al content of different zeolites play a crucial role in determining the trapping ability.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Chang-Xin Zhao, Jia-Ning Liu, Changda Wang, Juan Wang, Li Song, Bo-Quan Li, Qiang Zhang
Summary: This study reveals the anionic regulation mechanism of sulfide electrocatalysts under working oxygen evolution conditions, leading to the formation of a stable oxysulfide structure as the actual active site for oxygen evolution electrocatalysis. This finding provides a fundamental understanding of surface reconstruction and active sites of sulfide oxygen evolution electrocatalysts and inspires the design of advanced multi-anion compounds for rational electrocatalysis.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Xiaoxuan Yang, Shreya Mukherjee, Thomas O'Carroll, Yang Hou, Meenesh R. Singh, Joseph A. Gauthier, Gang Wu
Summary: Unrestrained anthropogenic activities disrupt the global natural nitrogen cycle, leading to energy and environmental issues. Electrocatalytic nitrogen transformation offers a feasible and promising strategy for a sustainable nitrogen economy. By synergistically combining multiple nitrogen reactions, efficient renewable energy storage and conversion, nitrogen balance restoration, and environmental crisis remediation can be achieved.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Yongxiang Liang, Jiankang Zhao, Yu Yang, Sung-Fu Hung, Jun Li, Shuzhen Zhang, Yong Zhao, An Zhang, Cheng Wang, Dominique Appadoo, Lei Zhang, Zhigang Geng, Fengwang Li, Jie Zeng
Summary: The authors report a coordination polymer catalyst with isolated neighboring copper sites that can efficiently reduce CO2 to C2H4 with high selectivity and stability under electrochemical conditions. This finding is significant for achieving net-zero carbon emissions through electrochemical CO2 reduction with renewable electricity.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Rongrong Li, Xinzheng Yang, Wei Guan
Summary: Density functional theory calculations reveal the radical mechanism of photocatalytic defluoroalkylation and hydrodefluorination of N-phenyl-2,2,2-trifluoromethylacetamide with o-phosphinophenolate cooperative catalysis, and computationally predict a series of available organic structures as potential substrates.
CHEMICAL COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Yuyang Kang, Lei Wang, Xiaoxiang Xu, Xing-Qiu Chen, Lianzhou Wang, Gang Liu
Summary: In this work, nitrogen doping was successfully achieved in BaLa4Ti4O15 via thermal treatment in an ammonia atmosphere. The nitrogen dopants were evenly distributed in the layered perovskite framework, leading to an extended band-to-band visible light absorption edge and efficient photocatalytic water oxidation activity under visible light.
ACS MATERIALS LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Yuyang Kang, Lei Wang, Xiaoxiang Xu, Xing-Qiu Chen, Lianzhou Wang, Gang Liu
Summary: This study successfully narrows the band gap of BaLa4Ti4O15 by nitrogen doping, while maintaining its crystal structure and microstructure. Homogeneous distribution of nitrogen dopants in the layered perovskite framework extends the visible light absorption range and enhances photocatalytic water oxidation activity.
ACS MATERIALS LETTERS
(2022)
Review
Chemistry, Multidisciplinary
Yalan Wang, Ping Hu, Jia Yang, Yi-An Zhu, De Chen
Summary: Alkanes as feedstocks play a crucial role in the chemical industry, and the activation of C-H bonds in light alkanes has attracted widespread attention due to the increasing global demand for light alkenes and synthesis gas. The theoretical understanding of this process through DFT and microkinetic modeling provides insights into catalyst design. This review focuses on the activation of methane, ethane, and propane on various surfaces with an emphasis on suppressing side reactions and coke formation.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Organic
Jiaxing Chen, Yongzhuo Xu, Wen Shao, Jianhua Ji, Boqiang Wang, Muyang Yang, Guojiang Mao, Fuhong Xiao, Guo-Jun Deng
Summary: A Pd-catalyzed C-O cross-coupling reaction was reported, which allows for the synthesis of highly congested hydroxylamines with an α-quaternary carbon center without cleavage of the N-O bond. This strategy shows high chemoselectivity, broad substrate scope, and excellent functional group tolerance, and has been demonstrated by pharmaceutical derivatization and postcatalytic modifications.
Article
Physics, Applied
Soichiro Shibasaki, Yuya Honishi, Naoyuki Nakagawa, Mutsuki Yamazaki, Yukitami Mizuno, Yasutaka Nishida, Kanta Sugimoto, Kazushige Yamamoto
Summary: Highly transparent Cu2O thin films were fabricated on a glass substrate using reactive sputtering with carefully controlled O-2 flow. The dependence of transmittance on impurities in the Cu2O thin films was thoroughly investigated, showing significant impact on both transmittance and photovoltaic properties. The lowest-impurity Cu2O thin film exhibited a maximum efficiency of 8.4%.
APPLIED PHYSICS LETTERS
(2021)
Article
Chemistry, Physical
Paul A. Pepin, Benjamin T. Diroll, Hyuck J. Choi, Christopher B. Murray, John M. Vohs
JOURNAL OF PHYSICAL CHEMISTRY C
(2017)
Article
Chemistry, Applied
Paul A. Pepin, Benjamin T. Diroll, Christopher B. Murray, John M. Vohs
TOPICS IN CATALYSIS
(2018)
Article
Chemistry, Applied
Daming Shi, John M. Vohs
Article
Chemistry, Physical
Cong Wang, Alexander V. Mironenko, Abhishek Raizada, Tianqi Chen, Xinyu Mao, Ashwin Padmanabhan, Dionisios G. Vlachos, Raymond J. Gorte, John M. Vohs
Article
Chemistry, Physical
Paul A. Pepin, Jennifer D. Lee, Christopher B. Murray, John M. Vohs
Article
Chemistry, Physical
Paul A. Pepin, Jennifer D. Lee, Alexandre C. Foucher, Christopher B. Murray, Eric A. Stach, John M. Vohs
JOURNAL OF PHYSICAL CHEMISTRY C
(2019)
Article
Chemistry, Physical
Yuan Cheng, Abhinav S. Raman, Julian Paige, Liang Zhang, Danyi Sun, Mavis U. Chen, Aleksandra Vojvodic, Raymond J. Gorte, John M. Vohs
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2019)
Article
Chemistry, Physical
Julian M. Paige, Yuan Cheng, Paul A. Pepin, Christopher D. Curran, Danyi Sun, Mavis U. Chen, Steven Mclntosh, John M. Vohs, Raymond J. Gorte
SOLID STATE IONICS
(2019)
Article
Chemistry, Physical
Tianqi Chen, John M. Vohs
Article
Chemistry, Physical
Tianyu Cao, Renjing Huang, Raymond J. Gorte, John M. Vohs
APPLIED CATALYSIS A-GENERAL
(2020)
Article
Chemistry, Physical
Arim Seong, Jeongwon Kim, Ohhun Kwon, Hu Young Jeong, Raymond J. Gorte, John M. Vohs, Guntae Kim
Article
Chemistry, Physical
Jian Chang, Zhuoming Feng, John M. Vohs, Raymond J. Gorte
Summary: The water-gas-shift (WGS) reaction was studied on Cu catalysts supported on modified MgAl2O4 (MAO) support using Atomic Layer Deposition (ALD) method. The study found that Cu/MAO catalysts prepared by ALD exhibited higher activity, while Cu catalysts with ZnO, CeO2, and Mn2O3 films showed minimal differences in activity compared to Cu/MAO catalyst. Cu catalysts prepared on CoO films showed slightly lower activity.
Article
Chemistry, Inorganic & Nuclear
Ching-Yu Wang, Kai Shen, Raymond J. Gorte, John M. Vohs
Summary: A simple method for incorporating various catalytic metals into the pores of SBA-15 using vapor-phase infiltration is presented. The study utilized Atomic Layer Deposition (ALD) to expose metal precursors on SBA-15, forming monolayer films inside the mesopores. The size and loading of the metal particles were determined using characterization techniques. The effect of surface composition on catalytic performance was also investigated.
Proceedings Paper
Electrochemistry
Y. Cheng, T. Oh, M. Rahmanipour, R. Wilson, R. J. Gorte, J. M. Vohs
SOLID OXIDE FUEL CELLS 15 (SOFC-XV)
(2017)
Article
Materials Science, Ceramics
Tianyu Cao, Yuan Cheng, Raymond J. Gorte, Yixiang Shi, John M. Vohs, Ningsheng Cai
CERAMICS INTERNATIONAL
(2017)
Article
Chemistry, Physical
Yifan Sun, Ye Lv, Wei Li, Jinli Zhang, Yan Fu
Summary: In this study, PtRu electrocatalysts were fabricated on carbon paper via cyclic electrodeposition for the electrocatalytic hydrogenation (ECH) of phenol. The Pt3Ru3 catalyst exhibited excellent activity and stability for the conversion of phenol to cyclohexanol at ambient temperature and various current densities. The in situ Raman spectroscopy and kinetic study revealed the hydrogenation mechanism of phenol over Pt3Ru3 in acidic electrolyte, providing an effective electrochemical strategy for the facile construction of durable electrode materials and efficient phenol hydrogenation.
JOURNAL OF CATALYSIS
(2024)
Article
Chemistry, Physical
Amir Shahzad, Khezina Rafiq, Muhammad Zeeshan Abid, Naseem Ahmad Khan, Syed Shoaib Ahmad Shah, Raed H. Althomali, Abdul Rauf, Ejaz Hussain
Summary: Photocatalytic hydrogen production through water splitting is an effective method for meeting future energy demands. In this study, researchers synthesized a 1 % Ag2S/Cu2S co-doped CdZnS catalyst and found that it can produce hydrogen at a higher rate. The co-doping of Ag2S and Cu2S in the CdZnS catalyst showed a synergistic effect, with Ag2S promoting oxidation reactions and Cu2S promoting reduction reactions.
JOURNAL OF CATALYSIS
(2024)