4.0 Article

Effect of Increasing the Common Anion Concentration on the Acid Hydrolysis of Glycosides

Journal

JOURNAL OF CARBOHYDRATE CHEMISTRY
Volume 32, Issue 4, Pages 223-239

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/07328303.2013.800085

Keywords

Carbohydrate; Counterion; Pinacol; Saccharification; Sugar; Sulfuric acid

Ask authors/readers for more resources

Acid hydrolysis of glycoside compounds, methyl - and -d-glucopyranosides, was accelerated when KCl or KBr was added to an HCl or HBr system, respectively, consisting of H2O or aqueous 1,4-dioxane. The proton activity and solvent dissociation power of the system were not changed by the addition of the salt. These results confirm our previous suggestion that Br- and Cl- directly participate in the hydrolysis reaction. The extent of participation of the anions was also estimated.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.0
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available